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https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778021 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778021.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_778021/ public [dis_15N2_gas] - Analysis of dissolved 15N2 gas standards by Membrane Inlet Mass Spectrometry (EAGER:  Collaborative Research:  Detection limit in marine nitrogen fixation measurements - Constraints of rates from the mesopelagic ocean) In order to verify that measurements of the 15N2 atom% of dissolved N2 gas samples effectuated by Membrane Inlet Mass Spectrometry are accurate, we developed a specific protocol to prepare dissolved 15N2 gas standards. We detail the protocol herein, and report representative MIMS measurements of the prepared standards.\n\ncdm_data_type = Other\nVARIABLES:\nBottle_vol (mililiters (mL))\nSample (unitless)\nInjection_15N2 (Injection 15 N2, mililiters (mL))\nExpected_15N_At_pcnt (Expected 15 N At Pcnt, unitless)\nTime_of_analysis (unitless)\nm_z_28 (unitless)\nm_z_29 (unitless)\nm_z_30 (unitless)\nm_z_32 (unitless)\nm_z_40 (unitless)\nN2_Ar (unitless)\nratio_28_29 (unitless)\nratio_28_30 (unitless)\nAt_15N_pcnt (At 15 N Pcnt, unitless)\nAt_15N_pcnt_avg (At 15 N Pcnt Avg, unitless)\n https://erddap.bco-dmo.org/erddap/metadata/iso19115/xml/bcodmo_dataset_778021_iso19115.xml https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_778021/index.htmlTable https://www.bco-dmo.org/dataset/778021 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_778021.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_778021&showErrors=false&email= BCO-DMO bcodmo_dataset_778021
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_743867 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_743867.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_743867/ public [Global Noble Gases] - A compilation of dissolved noble gas and N2/Ar ratio measurements collected from 1999-2016 in locations spanning the globe (Carbon Dioxide Dynamics in Mode Water of the North Atlantic Ocean ) Inert gases dissolved in the ocean are powerful tracers of the impact of physical processes on gases, particularly air-sea gas exchange (by both diffusive and bubble-meditated processes), temperature change, atmospheric pressure variation, mixing between different water masses, and ice processes. We have compiled a global ocean database of dissolved neon, argon, and krypton measurements, supplemented by helium, xenon, and nitrogen/argon (N2/Ar) ratios in some locations. Samples were collected on board multiple research cruises spanning the period 1999 through 2016 and analyzed by mass spectrometry at four different shore-based laboratories (University of Victoria, Woods Hole Oceanographic Institution, University of Washington, and Scripps Institution of Oceanography).\n\ncdm_data_type = Other\nVARIABLES:\nsequence (unitless)\ncruise_name (unitless)\nlatitude (degrees_north)\nlongitude (degrees_east)\nevent (unitless)\nstation (unitless)\ncast (unitless)\nniskin (unitless)\nyear (unitless)\nmonth (unitless)\nday (unitless)\npress (decibars (dbar))\nCTDtemp (degrees Celsius)\nCTDsal (unitless)\nanalysis_lab (unitless)\nsecondary_analysis_lab (unitless)\nHe_conc (micromoles per kilogram (umol/kg))\nHe_conc2 (micromoles per kilogram (umol/kg))\nNe_conc (micromoles per kilogram (umol/kg))\n... (40 more variables)\n https://erddap.bco-dmo.org/erddap/metadata/fgdc/xml/bcodmo_dataset_743867_fgdc.xml https://erddap.bco-dmo.org/erddap/metadata/iso19115/xml/bcodmo_dataset_743867_iso19115.xml https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_743867/index.htmlTable https://www.bco-dmo.org/dataset/743867 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_743867.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_743867&showErrors=false&email= BCO-DMO bcodmo_dataset_743867
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778083 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778083.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_778083/ public [mz_30_int_from_o2] - Test of potential mass to charge 30 interferences from O2 (EAGER:  Collaborative Research:  Detection limit in marine nitrogen fixation measurements - Constraints of rates from the mesopelagic ocean) Molecular oxygen (O2) has been documented to ionize partially to NO+ in mass spectrometer sources, generating a signal that overlaps with that of 15N2 (mass-to-charge of 30). Here, we tested whether O2 needs to be specifically removed from the sample streams of the Membrane Inlet Mass Spectrometer and the Isotope Ratio Mass Spectrometer in order to properly quantitate 15N2 atom% at pertinent concentrations. Sample streams with and without O2 yielded similar signals, suggesting that O2 does not interfere with the 15N2 atom% measurements in the experimental range with the given instruments.\n\ncdm_data_type = Other\nVARIABLES:\nSample (unitless)\nTime_of_analysis (unitless)\nm_z_28 (unitless)\nm_z_29 (unitless)\nm_z_30 (unitless)\nm_z_32 (unitless)\nm_z_40 (unitless)\nN2_Ar (unitless)\nratio_28_29 (unitless)\nratio_28_30 (unitless)\natom_pcnt_15n (unitless)\nNotes (unitless)\n https://erddap.bco-dmo.org/erddap/metadata/iso19115/xml/bcodmo_dataset_778083_iso19115.xml https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_778083/index.htmlTable https://www.bco-dmo.org/dataset/778083 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_778083.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_778083&showErrors=false&email= BCO-DMO bcodmo_dataset_778083
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778126 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778126.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_778126/ public [trial_a] - Trial A test of the dissolution method for estimates of the 15N2 atom% of incubations (EAGER:  Collaborative Research:  Detection limit in marine nitrogen fixation measurements - Constraints of rates from the mesopelagic ocean) The \\u201cdissolution\\u201d method to measure N2 fixation rates with 15N2 gas tracer involves the preparation of 15N2-enriched water that is then added to each incubation bottle. Investigators typically measure the 15N2 atom% of the 15N2-enriched inoculum by MIMS, and extrapolate the 15N2 atom% in the incubations based on the inoculum value. Here, we demonstrate that such extrapolation yields inaccurate estimates of the 15N2 atom% of incubations. The latter should be measured directly.\n\ncdm_data_type = Other\nVARIABLES:\nSample (unitless)\nBaro_Press (unknown)\nTime_of_analysis (unitless)\nm_z_28 (unitless)\nm_z_29 (unitless)\nm_z_30 (unitless)\nm_z_32 (unitless)\nm_z_40 (unitless)\nN2_Ar (unitless)\nratio_28_29 (unitless)\nratio_28_30 (unitless)\nmeas_at_pcnt (unitless)\navg_measured_a_pcnt (unitless)\n https://erddap.bco-dmo.org/erddap/metadata/iso19115/xml/bcodmo_dataset_778126_iso19115.xml https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_778126/index.htmlTable https://www.bco-dmo.org/dataset/778126 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_778126.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_778126&showErrors=false&email= BCO-DMO bcodmo_dataset_778126

 
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