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log in [EXPORTS NA nuts and TM field data] - Dissolved trace metal and macronutrient concentrations rom field samples collected during the EXPORTS North Atlantic campaign at the Porcupine Abyssal Plain-Sustained Observatory (PAP-SO) site on board the RRS Discovery (DY131) in May 2021 (Collaborative Research: Diatoms, Food Webs and Carbon Export - Leveraging NASA EXPORTS to Test the Role of Diatom Physiology in the Biological Carbon Pump) This dataset includes dissolved trace metal (manganese, iron, cobalt, nickel, copper, cadmium, zinc, lead) and macronutrient (nitrate+nitrite, phosphate, silicic acid, nitrite) concentration data from field samples collected during the EXPORTS North Atlantic campaign at the Porcupine Abyssal Plain-Sustained Observatory (PAP-SO) site on board the RRS Discovery (DY131). These data were primarily collected opportunistically during the course of water collection for incubation experiments (see separate dataset for incubations), and provide field context for the shipboard incubation experiments as well as temporal characterization of a retentive anticyclonic eddy occupied over the course of the cruise.\n\nThis research focuses on the vertical export of the carbon associated with a major group of phytoplankton, the diatoms in the North Atlantic near the Porcupine Abyssal Plain. The major objective is to understand how diatom community composition and the prevailing nutrient conditions create taxonomic differences in metabolic state that combine to direct diatom taxa to different carbon export pathways. The focus is on diatoms, given their large contribution to global marine primary productivity and carbon export which translates into a significant contribution to the biogeochemical cycling of carbon (C), nitrogen (N), phosphorus (P), iron (Fe) and silicon (Si). It is hypothesized that the type and degree of diatom physiological stress are vital aspects of ecosystem state that drive export. To test this hypothesis, combined investigator expertise in phytoplankton physiology, genomics, and trace element chemistry is used to assess the rates of nutrient use and the genetic composition and response of diatom communities, with measurements of silicon and iron stress to evaluate stress as a predictor of the path of diatom carbon export. The EXPORTS field campaign in the North Atlantic sampled a retentive eddy over nearly a month in May 2021, which coincided with the decline of the North Atlantic Spring Bloom.\n\ncdm_data_type = Other\nVARIABLES:\nCRUISE_ID (unitless)\nEVTNBR (unitless)\nDATE_UTC (unitless)\nTIME_UTC (unitless)\ntime (Iso_datetime_utc, seconds since 1970-01-01T00:00:00Z)\n... (90 more variables)\n BCO-DMO bcodmo_dataset_954941_v1
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_792817 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_792817.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_792817/ public [Lagrangian Trace Metal Concentrations] - Surface and profile concentrations of trace metals and radionuclides near Station ALOHA (Center for Microbial Oceanography: Research and Education) Trace element water samples from KM1513 were collected with the MIT Automated Trace Element (ATE) sampler, deployed with a teflon-coated wire from the ship\\u2019s deck for surface water samples (collected at roughly 10 m depth), and with the ATEs attached to PVC \\u201cVanes\\u201d designed to prevent contamination from the ship\\u2019s steel wire for samples collected at greater depth. Samples were filtered at 0.4 \\u03bcm immediately after collection through polycarbonate track etched filters (Nucleopore) into 250 mL HDPE bottles and acidified to 0.012 M hydrochloric acid (ultrapure by quadruple distillation in a Vycor still; ~pH 2) at sea. Sampling and filtration followed published protocols used previously at Station ALOHA, for direct comparison (Fitzsimmons et al., 2015). These casts mostly aligned with Niskin cast station locations, but in some cases did not.\n\ncdm_data_type = Other\nVARIABLES:\nCruise (unitless)\nSample_Time (unitless)\ndepth (m)\nUnit_Cast_Niskin (unitless)\nlatitude (degrees_north)\nlongitude (degrees_east)\nMn_D_CONC (nanomole per kilogram (nmole/kg))\nMn_D_CONC_ERROR (nanomole per kilogram (nmole/kg))\nFe_D_CONC (nanomole per kilogram (nmole/kg))\nFe_D_CONC_ERROR (nanomole per kilogram (nmole/kg))\nCo_L_CONC (picomole per kilogram (pmole/kg))\nCo_L_CONC_ERROR (picomole per kilogram (pmole/kg))\nNi_D_CONC (nanomole per kilogram (nmole/kg))\nNi_D_CONC_ERROR (nanomole per kilogram (nmole/kg))\nCu_D_CONC (nanomole per kilogram (nmole/kg))\nCu_D_CONC_ERROR (nanomole per kilogram (nmole/kg))\nZn_D_CONC (nanomole per kilogram (nmole/kg))\nZn_D_CONC_ERROR (nanomole per kilogram (nmole/kg))\n... (15 more variables)\n https://erddap.bco-dmo.org/erddap/metadata/fgdc/xml/bcodmo_dataset_792817_fgdc.xml https://erddap.bco-dmo.org/erddap/metadata/iso19115/xml/bcodmo_dataset_792817_iso19115.xml https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_792817/index.htmlTable https://www.bco-dmo.org/dataset/792817 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_792817.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_792817&showErrors=false&email= BCO-DMO bcodmo_dataset_792817
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_1002908_v1 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_1002908_v1.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_1002908_v1/ public [Long-term EXPORTS 2018 North Pacific incubation data] - Dissolved and labile particulate elemental, dissolved macronutrient, chlorophyll a, biogenic silica, and particulate organic carbon and nitrogen from four shipboard incubation experiments from the 2018 EXPORTS cruise (RR1813) near Ocean Station PAPA (Collaborative Research: Diatoms, Food Webs and Carbon Export - Leveraging NASA EXPORTS to Test the Role of Diatom Physiology in the Biological Carbon Pump) This dataset includes the concentrations of dissolved (<0.4 micrometer (µm)) nickel (Ni), cadmium (Cd), soluble reactive phosphorus (\"phosphate\"), nitrite (NO3-), nitrate+nitrite (NO3-+NO2-), and silicic acid (Si(OH)4) from four long-term (6- to 8-day) incubations conducted during the EXports Processes in the Oceans from RemoTe Sensing (EXPORTS) North Pacific (NP) cruise on the R/V Roger Revelle (RR1813) near Ocean Station Papa. Additionally, concentrations of size-fractionated (0.6-5 µm and >5 µm) chlorophyll a and biogenic silica (bSi); size-fractionated (0.4-5 µm and >5 µm) labile particulate elemental phosphorus (P), Ni, and Cd; and particulate organic carbon and nitrogen (POC and PON, respectively) from these four incubations was measured. Treatments included various additions of macronutrients and/or iron (Fe) to either induce severe nutrient stress or relieve nutrient limitation. For each incubation, triplicate initial control samples were collected and then triplicate samples from each treatment were collected on the final day. This study provides insight into the macronutrient-micronutrient levers that may be responsible for the lack of full dissolved Ni depletion in ocean surface waters by marine phytoplankton.\n\ncdm_data_type = Other\nVARIABLES:\nCRUISE (unitless)\nSAMPLE_DATE (unitless)\nJULIAN_DAY (unitless)\nEPOCH (unitless)\nEPOCH_DAY (unitless)\nINCUBATION (unitless)\nTIMEPOINT (unitless)\nTREATMENT (unitless)\nREPLICATE (unitless)\nPHOSPHATE (micromolar (µM))\nPHOSPHATE_flag (unitless)\nSILICIC_ACID (micromolar (µM))\nSILICIC_ACID_flag (unitless)\nNITRITE (micromolar (µM))\nNITRITE_flag (unitless)\n... (34 more variables)\n https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_1002908_v1/index.htmlTable https://osprey.bco-dmo.org/dataset/1002908 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_1002908_v1.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_1002908_v1&showErrors=false&email= BCO-DMO bcodmo_dataset_1002908_v1
log in [STING Endmember Metals] - Dissolved trace metal concentrations from submarine groundwater wells, rivers and estuaries sampled along the West Florida Shelf for the STING project between November 2022 and March 2024 (Collaborative Research: Linking iron and nitrogen sources in an oligotrophic coastal margin: Nitrogen fixation and the role of boundary fluxes) Concentrations of dissolved trace metals (Al, Mn, Fe, Co, Ni, Cu, Zn, Mo, Cd, Ba, Lu, Pb) from submarine groundwater wells and overlying water column, and from rivers and estuaries sampled along the West Florida Shelf.\n\nThis project investigates how groundwater discharge delivers important nutrients to the coastal ecosystems of the West Florida Shelf. Preliminary studies had indicated that groundwater may supply both dissolved organic nitrogen (DON) and iron in this region. In coastal ecosystems like the West Florida Shelf that have very low nitrate and ammonium concentrations, DON is the main form of nitrogen available to organisms. Nitrogen cycling is strongly affected by iron availability because iron is essential for both photosynthesis and for nitrogen fixation. This study investigated the sources and composition of DON and iron, and their influence on the coastal ecosystem. The team sampled offshore groundwater wells, river and estuarine waters from shore, and conducted two expeditions across the West Florida Shelf in winter and summer for surface and depth profile sampling and for shipboard incubation experiments.\n\ncdm_data_type = Other\nVARIABLES:\nSTING_ID (unitless)\nCRUISE_ID (unitless)\ntime (Datetime_utc, seconds since 1970-01-01T00:00:00Z)\nDATETIME_LOCAL_ET (unitless)\nDATE_LOCAL (unitless)\nTIME_LOCAL (unitless)\nTIME_ZONE (unitless)\nlatitude (degrees_north)\nlongitude (degrees_east)\nSTN (unitless)\nSAMPLE_ID (unitless)\nSAMPLE_DESC (unitless)\nSITE_TYPE (unitless)\nPLATFORM (unitless)\n... (56 more variables)\n BCO-DMO bcodmo_dataset_997829_v1
log in [STING I Dissolved Soluble Trace Metals] - Concentrations of soluble and dissolved trace metals in water column samples and incubation experiments from STING I cruise AE2305 on R/V Atlantic Explorer over the West Florida Shelf from February to March 2023 (Collaborative Research: Linking iron and nitrogen sources in an oligotrophic coastal margin: Nitrogen fixation and the role of boundary fluxes) This dataset includes concentrations of soluble and dissolved trace metals (Al, Sc, Mn, Fe, Co, Ni, Cu, Zn, Cd, Gd, Lu, Pb) from phytoplankton shipboard incubation experiments and water column samples collected on STING I cruise AE2305 on R/V Atlantic Explorer over the West Florida Shelf from February to March 2023.\n\nThis project investigates how groundwater discharge delivers important nutrients to the coastal ecosystems of the West Florida Shelf. Preliminary studies had indicated that groundwater may supply both dissolved organic nitrogen (DON) and iron in this region. In coastal ecosystems like the West Florida Shelf that have very low nitrate and ammonium concentrations, DON is the main form of nitrogen available to organisms. Nitrogen cycling is strongly affected by iron availability because iron is essential for both photosynthesis and for nitrogen fixation. This study investigated the sources and composition of DON and iron, and their influence on the coastal ecosystem. The team sampled offshore groundwater wells, river and estuarine waters from shore, and conducted two expeditions across the West Florida Shelf in winter and summer for surface and depth profile sampling and for shipboard incubation experiments.\n\ncdm_data_type = Other\nVARIABLES:\nSTING_ID (unitless)\nCRUISE_ID (unitless)\nEVTNBR (unitless)\ntime (Datetime_utc, seconds since 1970-01-01T00:00:00Z)\nDATE_UTC (unitless)\nTIME_UTC (unitless)\nDATETIME_EST (unitless)\nDATE_EST (unitless)\nTIME_EST (unitless)\nlatitude (Latitude_ship, degrees_north)\nlongitude (Longitude_ship, degrees_east)\nPLATFORM (unitless)\nCASTNBR (unitless)\n... (116 more variables)\n BCO-DMO bcodmo_dataset_997813_v1
log in [STING II Dissolved Trace Metals] - Dissolved trace metal concentrations in water column samples and incubation experiments from STING II cruise EN704 on R/V Endeavor over the West Florida Shelf in July 2023 (Collaborative Research: Linking iron and nitrogen sources in an oligotrophic coastal margin: Nitrogen fixation and the role of boundary fluxes) Concentrations of dissolved trace metals (Al, Sc, Mn, Fe, Co, Ni, Cu, Zn, Cd, Gd, Lu, Pb) in phytoplankton shipboard incubation experiments and water column samples collected on STING II cruise EN704 on R/V Endeavor over the West Florida Shelf in July 2023.\nThis project investigates how groundwater discharge delivers important nutrients to the coastal ecosystems of the West Florida Shelf. Preliminary studies had indicated that groundwater may supply both dissolved organic nitrogen (DON) and iron in this region. In coastal ecosystems like the West Florida Shelf that have very low nitrate and ammonium concentrations, DON is the main form of nitrogen available to organisms. Nitrogen cycling is strongly affected by iron availability because iron is essential for both photosynthesis and for nitrogen fixation. This study investigated the sources and composition of DON and iron, and their influence on the coastal ecosystem. The team sampled offshore groundwater wells, river and estuarine waters from shore, and conducted two expeditions across the West Florida Shelf in winter and summer for surface and depth profile sampling and for shipboard incubation experiments.\n\ncdm_data_type = Other\nVARIABLES:\nSTING_ID (unitless)\nCRUISE_ID (unitless)\nEVTNBR (unitless)\ntime (Datetime_utc, seconds since 1970-01-01T00:00:00Z)\nDATE_UTC (unitless)\nTIME_UTC (unitless)\nDATETIME_EDT (unitless)\nDATE_EDT (unitless)\nTIME_EDT (unitless)\nlatitude (Latitude_ship, degrees_north)\nlongitude (Longitude_ship, degrees_east)\nPLATFORM (unitless)\nCASTNBR (unitless)\nSTNNBR (unitless)\nLATITUDE_map (degrees_north)\n... (62 more variables)\n BCO-DMO bcodmo_dataset_997847_v1

 
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