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https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_925782_v1 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_925782_v1.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_925782_v1/ public [Cr concentration and isotopic composition of Cr(III) and Cr(VI) in the ETNP from RR1804-05 and KM1919-20] - Chromium concentration and isotopic composition of Cr(III) and Cr(VI) in the Eastern Tropical North Pacific from samples collected on R/V Roger Revelle and R/V Kilo Moana in April-May 2018 and Sept-Oct 2019 (Cr Isotope Oceanography of the Eastern Tropical North Pacific Ocean) Understanding the cycling of chromium (Cr) and how chromium stable isotopes (δ53Cr) are altered in response to different processes in the modern ocean is important in our interpretation of marine sedimentary δ53Cr records, a promising redox proxy. Therefore, it is crucial to investigate the geochemical processes of Cr in reducing environments such as oxygen deficient zones (ODZs). In this study, we investigated the cycling of Cr in the Eastern Tropical North Pacific (ETNP) ODZ by analyzing the [Cr] and δ53Cr of total dissolved Cr and Cr(III). Our Cr(III) data at two inshore stations shows profile features and Cr reduction isotopic fractionation factor (-1.5‰) similar to an offshore station in a previous study. We also observed significant Cr scavenging signals in the upper 1000 meters (m) throughout the ODZ with an inshore-offshore variability in its magnitude. Specifically, anoxic bottom waters on the continental slope see the greatest Cr scavenging with heaviest δ53Cr (+1.85‰). Our estimates of the scavenged Cr isotopic composition are within error of the anoxic and euxinic marine sedimentary δ53Cr. This implies that the vertical transport of Cr to the seafloor and subsequent diagenesis may not generate significant isotopic fractionation for Cr. This is the first thorough investigation into the Cr cycling in the ETNP ODZ and demonstrated promising usage of marine sedimentary δ53Cr as a redox proxy for ancient oceans.\n\nIn the ODZ, oxygen is consumed by degrading sinking particles and reaches extremely low levels (too low to support aerobic life) from 100m to 800m depth. However, microbes that can use other oxidants such as nitrate to metabolize organic carbon live there, and we showed that they also convert soluble anionic chromate Cr(VI) to cationic Cr(III), about half of which is scavenged onto sinking particles and removed to the seafloor. This reduction is accompanied by preferential reduction of light Cr isotopes, so the Cr(III) is 1.3‰ lighter than the source Cr(VI). The removal of part of this light Cr(III) by scavenging leaves the residual total Cr heavier than the source Cr. The analyzed samples listed here were chosen to be from the center and margins of the ETNP ODZ and over extremely reducing continental margin sediments.\n\ncdm_data_type = Other\nVARIABLES:\nCruise (unitless)\nStation (unitless)\nLatitude (degrees_north)\n... (9 more variables)\n https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_925782_v1/index.htmlTable https://www.bco-dmo.org/dataset/925782 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_925782_v1.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_925782_v1&showErrors=false&email= BCO-DMO bcodmo_dataset_925782_v1
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_914105_v1 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_914105_v1.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_914105_v1/ public [OOI Argentine Basin CTD and Water Sampling Data] - OOI CTD and Discrete Water Sampling Data from R/V Atlantis, RVIB Nathaniel B. Palmer AT26-30, AT39-03, NBP1510, NBP1609 in the Argentine Basin from 2015-2018 (OOI Water Sample Data project) (OOI Discrete CTD and Water Sampling Cruise Data) The hydrographic sampling performed by OOI-CGSN (the Ocean Observatories Initiative - Coastal and Global Scale Nodes) part of each Array turn represents a significant collection of valuable physical, chemical, and biological information. In addition to the CTD, collected hydrographic data include discrete oxygen, salinity, nutrient (nitrate, nitrite, silicate, phosphate, ammonium), chlorophyll, and carbon system measurements. These data serve several important functions. First, they are necessary for the calibration and evaluation of the moored instrumentation at each Array. Furthermore, the annual (Global) or biannual (Coastal) collection of data at the same locations provides a unique time series of a large set of water properties following established community standards and methods, independent of its association with the OOI moorings.\n\nThe analyses of collected water samples for the parameters listed above are performed by a number of outside labs on behalf of OOI-CGSN. Consequently, the water sampling data for a given cruise is distributed among a number of different files. The Discrete Sampling Summary integrates the related CTD, metadata, and discrete water sample data into a single file. Additionally, it synthesizes qualitative and quantitative information about the quality of a measurement into data quality flags for each associated parameter which follow WOCE-standards.\n\nThe final product is the Discrete Sampling Summary spreadsheet which contains the metadata, CTD data and discrete water sample data into a single spreadsheet with data quality flags.\n\nThis dataset includes hydrographic data from the Global Argentine Basin Array, which was located in the South Atlantic from March 2015 to January 2018. The Argentine Basin Array was useful for exploring the global carbon cycle because of its high biological productivity fueled by iron-laden dust from South America. With strong currents persisting on the seafloor and water mass mixing, this region has elevated levels of eddy kinetic energy similar to those in the Gulf Stream.\n\ncdm_data_type = Other\nVARIABLES:\nCruise (unitless)\nStation (unitless)\nTarget_Asset (unitless)\n... (76 more variables)\n https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_914105_v1/index.htmlTable https://www.bco-dmo.org/dataset/914105 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_914105_v1.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_914105_v1&showErrors=false&email= BCO-DMO bcodmo_dataset_914105_v1
log in [OOI Southern Ocean Array CTD and Water Sampling Data] - OOI Global Southern Ocean Array CTD and Discrete Water Sampling Data from R/V Atlantis, RVIB Nathaniel B. Palmer, RRS Discovery AT26-29, NBP1511, NBP1610, NBP1709, DY096, DY112 in the Southern Pacific Ocean from 2015-2020 (OOI Cruise Data project) (OOI Discrete CTD and Water Sampling Cruise Data) The hydrographic sampling performed by OOI-CGSN (the Ocean Observatories Initiative - Coastal and Global Scale Nodes) part of each Array turn represents a significant collection of valuable physical, chemical, and biological information. In addition to the CTD, collected hydrographic data include discrete oxygen, salinity, nutrient (nitrate, nitrite, silicate, phosphate, ammonium), chlorophyll, and carbon system measurements. These data serve several important functions. First, they are necessary for the calibration and evaluation of the moored instrumentation at each Array. Furthermore, the annual (Global) or biannual (Coastal) collection of data at the same locations provides a unique time series of a large set of water properties following established community standards and methods, independent of its association with the OOI moorings.\n\nThe analyses of collected water samples for the parameters listed above are performed by a number of outside labs on behalf of OOI-CGSN. Consequently, the water sampling data for a given cruise is distributed among a number of different files. The Discrete Sampling Summary integrates the related CTD, metadata, and discrete water sample data into a single file. Additionally, it synthesizes qualitative and quantitative information about the quality of a measurement into data quality flags for each associated parameter which follow WOCE-standards.\n\nThe final product is the Discrete Sampling Summary spreadsheet which contains the metadata, CTD data and discrete water sample data into a single spreadsheet with data quality flags.\n\nThis dataset includes hydrographic data from the Global Southern Ocean Array. The Global Southern Ocean Array was located in the high-latitude South Pacific, west of the Southern tip of Chile in an area of large scale thermohaline circulation, intermediate water formation , and CO2 sequestration. It permitted examination of linkages between the Southern Ocean and the Antarctic, including strengthening westerly winds and upwelling. This array was in place from February 2015 to January 2020 when it was removed.\n\ncdm_data_type = Other\nVARIABLES:\nCruise (unitless)\nStation (unitless)\n... (77 more variables)\n BCO-DMO bcodmo_dataset_923545_v1
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_925726_v1 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_925726_v1.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_925726_v1/ public [Total dissolved Cr concentration and isotopic composition in the ETNP from RR1804-05 and KM1919-20] - Total dissolved chromium (Cr) concentration and isotopic composition in the Eastern Tropical North Pacific from samples collected on R/V Roger Revelle and R/V Kilo Moana in April-May 2018 and Sept-Oct 2019 (Cr Isotope Oceanography of the Eastern Tropical North Pacific Ocean) Understanding the cycling of chromium (Cr) and how chromium stable isotopes (δ53Cr) are altered in response to different processes in the modern ocean is important in our interpretation of marine sedimentary δ53Cr records, a promising redox proxy. Therefore, it is crucial to investigate the geochemical processes of Cr in reducing environments such as oxygen deficient zones (ODZs). In this study, we investigated the cycling of Cr in the Eastern Tropical North Pacific (ETNP) ODZ by analyzing the [Cr] and δ53Cr of total dissolved Cr and Cr(III). Our Cr(III) data at two inshore stations shows profile features and Cr reduction isotopic fractionation factor (-1.5‰) similar to an offshore station in a previous study. We also observed significant Cr scavenging signals in the upper 1000 meters (m) throughout the ODZ with an inshore-offshore variability in its magnitude. Specifically, anoxic bottom waters on the continental slope see the greatest Cr scavenging with heaviest δ53Cr (+1.85‰). Our estimates of the scavenged Cr isotopic composition are within error of the anoxic and euxinic marine sedimentary δ53Cr. This implies that the vertical transport of Cr to the seafloor and subsequent diagenesis may not generate significant isotopic fractionation for Cr. This is the first thorough investigation into the Cr cycling in the ETNP ODZ and demonstrated promising usage of marine sedimentary δ53Cr as a redox proxy for ancient oceans.\n\nIn the ODZ, oxygen is consumed by degrading sinking particles and reaches extremely low levels (too low to support aerobic life) from 100m to 800m depth. However, microbes that can use other oxidants such as nitrate to metabolize organic carbon live there, and we showed that they also convert soluble anionic chromate Cr(VI) to cationic Cr(III), about half of which is scavenged onto sinking particles and removed to the seafloor. This reduction is accompanied by preferential reduction of light Cr isotopes, so the Cr(III) is 1.3‰ lighter than the source Cr(VI). The removal of part of this light Cr(III) by scavenging leaves the residual total Cr heavier than the source Cr. The analyzed samples listed here were chosen to be from the center and margins of the ETNP ODZ and over extremely reducing continental margin sediments.\n\ncdm_data_type = Other\nVARIABLES:\nCruise (unitless)\nStation (unitless)\nLatitude (degrees_north)\n... (5 more variables)\n https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_925726_v1/index.htmlTable https://www.bco-dmo.org/dataset/925726 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_925726_v1.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_925726_v1&showErrors=false&email= BCO-DMO bcodmo_dataset_925726_v1

 
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