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log in [Northern Gulf of Mexico pore geochemical data] - Depth profiles of pore water constituents from sediment cores collected on the Louisiana Shelf of the Northern Gulf of Mexico during 2020, 2021, and 2022 on R/V Savannah cruises SAV-20-07, SAV-21-25, SAV-21-24, SAV-22-06, and SAV-22-11 (Importance of Riverine Discharge on the Benthic Flux of Alkalinity to Continental Margins) This data set reports depth profiles of pore water concentrations of dissolved inorganic carbon (DIC), orthophosphate (PO43-), ammonium (NH4+), total alkalinity (TA), carbon isotopic fractionation of DIC (13C-DIC), dissolved manganese (Mnd), dissolved calcium (Cad), reduced iron (Fe(II)), total dissolved Fe (Fed), and dissolved Fe(III) (Fe(III)d) by the difference of total dissolved Fe and Fe(II). Data were collected during five R/V Savannah cruises in fall 2020, summer and fall 2021, and fall and spring 2022. On each cruise pore water data were obtained from sediment cores collected with an MC-800 multi-corer at multiple stations. Cruise IDs were: SAV-20-07, SAV-21-25, SAV-21-24, SAV-22-06, SAV-22-11.\n\nAll cores were processed within a few hours after collection. The pore waters were first extracted by slicing sediment cores of < 40 centimeters (cm) long and centrifugation of the pore waters under N2 atmosphere to avoid air contamination. Pore waters were then immediately filtered through 0.22-micrometer (um) PSE syringe filters under N2 atmosphere and either analyzed immediately onboard (Fe speciation, orthophosphate, DIC), preserved acidified with hydrochloric acid at 4 degrees Celsius (Cad, Mnd), frozen (ammonium), or preserved at 4 degrees Celsius after addition of HgCl2 (TA) until analysis.  In addition, samples for TA and carbon isotopic analyses were preserved in glass bottles, whereas other samples were preserved in polypropylene containers.\n\nDIC was analyzed by flow injection analysis (Hall and Aller, 1992), orthophosphate, ammonium, and Fe speciation by spectrophotometry (Murphy and Riley, 1962; Strickland and Parsons, 1972; Stookey, 1970), TA by Gran titration (Gran, 1952), the carbon isotopic signature by isotope ratio mass spectrometry (Wang et al, 2018), and Mnd and Cad by ICP-MS (Magette et al., 2025 In preparation).\n\ncdm_data_type = Other\nVARIABLES:\nYear (unitless)\nMonth (unitless)\nDay (unitless)\nDate (unitless)\nCollection_Type (unitless)\nStation (unitless)\n... (24 more variables)\n BCO-DMO bcodmo_dataset_904417_v2
https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_734364 https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_734364.graph https://erddap.bco-dmo.org/erddap/files/bcodmo_dataset_734364/ public [Shipboard bioassay experiments] - Dissolved inorganic nitrogen, chlorophyll-a, and primary production from bioassay experiments during the R/V Hugh R. Sharp cruise HRS1414 in the Mid and South-Atlantic Bight in August of 2014 (DANCE project) (Collaborative Research: Impacts of atmospheric nitrogen deposition on the biogeochemistry of oligotrophic coastal waters) Three bioassay experiments were conducted in August of 2014 during the R/V Hugh R. Sharp cruise HRS1414 which generated measurements of dissolved inorganic nitrogen, chlorophyll-a and primary productivity.  Treatments included various nutrient (N,Fe,P) additions and rainwater.\\r\\n\\r\\nThis dataset was utilized in the following publication:\\r\\nSedwick. P. N., et al. \\Assessing phytoplankton nutritional status and potential impact of wet deposition in seasonally oligotrophic waters of the Mid-Atlantic Bight.\\ Geophysical Research Letters (2018): doi: 10.1002/2017GL075361\n\ncdm_data_type = Other\nVARIABLES:\nexperiment (unitless)\ntreatment (unitless)\ntime2 (Time, hours)\nmean_NO3_NO2 (Mole Concentration Of Nitrate In Sea Water, micromoles per liter (umol/L))\nSD_NO3_NO2 (micromoles per liter (umol/L))\nmean_NH4 (micromoles per liter (umol/L))\nSD_NH4 (micromoles per liter (umol/L))\nmean_Chl_a (Concentration Of Chlorophyll In Sea Water, micrograms per liter (mg/L))\nSD_Chl_a (micrograms per liter (mg/L))\nmean_PP (micromoles C per liter per day (umol C/L/d))\nSD_PP (micromoles C per liter per day (umol C/L/d))\n https://erddap.bco-dmo.org/erddap/info/bcodmo_dataset_734364/index.htmlTable https://www.bco-dmo.org/dataset/734364 (external link) https://erddap.bco-dmo.org/erddap/rss/bcodmo_dataset_734364.rss https://erddap.bco-dmo.org/erddap/subscriptions/add.html?datasetID=bcodmo_dataset_734364&showErrors=false&email= BCO-DMO bcodmo_dataset_734364

 
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