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log in [High-Frequency CO2-system observations from a moored sensor in the York River] -  (Collaborative Research: Multiple Stressors in the Estuarine Environment: What drives changes in the Carbon Dioxide system?) These are CO2-system data from a moored sensor in the York River, a tributary of the Chesapeake Bay. Temperature, salinity and pH were acquired hourly over two deployments lasting several months. Sensor data were then averaged to 24-hour resolution. Data were calibrated with discrete dissolved inorganic carbon (TCO2) and alkalinity samples analyzed at the Virginia Institute of Marine Science, following standard procedures. The pH sensor data were then combined with salinity data, and a relationship between alkalinity and salinity, to compute the remaining CO2-system parameters (TCO2, CO2 partial pressure (pCO2), and saturation state of aragonite. There is one file for each deployment (D1, and D2); the data are in a comma-separated (csv) format. Hourly measured temperature, salinity, and pH are given, as well as derived alkalinity, TCO2, pCO2, and saturation state of aragonite are included. Units are in the first row of each file.\n\ncdm_data_type = Other\nVARIABLES:\nDate_Matlab (unitless)\ntime (Datetime, seconds since 1970-01-01T00:00:00Z)\nlatitude (degrees_north)\nlongitude (degrees_east)\nTemp_degC (degrees Celsius (°C))\nSalinity (unitless)\npH_total (unitless)\nalkalinity_umol_kg (micromole per Kilogram (umol/kg))\nTCO2_umol_kg (micromole per Kilogram (umol/kg))\npCO2_uatm (microatmospheres (uatm))\nWar (unitless)\nDeployment (unitless)\n BCO-DMO bcodmo_dataset_890566_v1
log in [Trace metal and organic iron ligand data] - Trace metal and organic iron ligand data collected during the PLUME RAIDERS cruise (RR2106) on the R/V Roger Revelle from 18 September – 6 November 2021 along the 16-18ºS section of the Southern East Pacific Rise. (Collaborative Research: Are Low-Temperature Hydrothermal Vents an Important but Overlooked Source of Stabilized Dissolved Iron to the Ocean?) This dataset includes the concentrations of total dissolvable iron and manganese, dissolved iron and manganese, and dissolved organic iron-binding ligands collected on the PLUME RAIDERS expedition. Samples were collected during the PLUME RAIDERS cruise (RR2106) on the R/V Roger Revelle from 18 September – 6 November 2021. The main study area was located along the 16-18ºS section of the Southern East Pacific Rise, and the sampling was focused near the ride crest at depths below 1,500 m. Both the total dissolvable and dissolved  iron and manganese concentrations were determined shipboard using flow injection analysis. The total organic iron-binding ligand data was  generated both shipboard and in the lab using competitive ligand exchange adsorptive cathodic stripping voltammetry. The siderophore concentrations were measured following a solid phase extraction step, and then eluents were measured using inductively coupled plasma mass spectrometry. The dissolvable and dissolved metal data was generated by Dr. Joe Resing and Nathan Buck at NOAA-PMEL and the ligand and siderophore data was generated by Dr. Laura Moore and Dr. Randelle Bundy at the University of Washington.\n\ncdm_data_type = Other\nVARIABLES:\nGT_number (unitless)\nCruise (unitless)\nStation (unitless)\nCast_number (unitless)\nRosette (unitless)\nSite_Name (unitless)\nStation_ID (unitless)\nBottle_Position (unitless)\nNisken_number (unitless)\nDate (unitless)\nTime_GMT (unitless)\ntime (Iso_datetime_utc, seconds since 1970-01-01T00:00:00Z)\nPressure_dbar (dbars)\ndepth (Depth_m, m)\nTemp_degC (degrees celsius)\n... (20 more variables)\n BCO-DMO bcodmo_dataset_944890_v1

 
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