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Row Type | Variable Name | Attribute Name | Data Type | Value |
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attribute | NC_GLOBAL | access_formats | String | .htmlTable,.csv,.json,.mat,.nc,.tsv |
attribute | NC_GLOBAL | acquisition_description | String | Natural seawater from the Gulf of Mexico with a salinity of 35.0 was filtered\nand ultrafiltered sequentially through a 0.4 \\u00b5m cartridge (GE-Osmonics)\nand a 1 kDa ultrafiltration membrane (Millipore-Amicon), to remove suspended\nparticles and colloidal matter. 210Po and 210Pb (in equilibrium) in 1 N HNO3-2\nN HCl were purchased from Eckert & Ziegler Isotopes Products. 7Be tracer was\nproduced at the Paul Scherrer Institute, Switzerland and preserved in 0.5 N\nHCl. All experiments were conducted in a constant temperature laboratory to\navoid the influence of changing temperature.\\u00a0\n \nFor sorption experiments, 49 ml of the <1 kDa ultrafiltrate of seawater in a\nstirred-cell unit was added with 1 ml of non-complexing Tris-HCl buffer\nsolution to maintain a constant pH of 8.1 and to prevent formation of pseudo-\ncolloids during the addition of spikes. For the single-sorbent experiments, 2\nmg of inorganic particles was added into the solution while stirring,\ncorresponding to a particle concentration of about 40 mg/l. Successively, a\ntotal of 0.2 ml of 210Pb, 210Pb and 7Be spikes, with the activities of 100 Bq,\n100 Bq and 150 Bq respectively, were added drop by drop while stirring.\\u00a0\nThe pH value was checked after adding spikes and found to be 8.1. For the\nsingle MOC experiments, procedures were the same as described above. The final\nconcentration of HA, APS or BSA was at 1 mg/l.\\u00a0\n \nAn equilibrium time of 2 h was consistently used in all experiments. After 2\nh, the particulate or colloidal phases were separated through ultrafiltration\nusing a 1 kDa membrane (Amicon YM1). The >1 kDa retentate (final volume of ~4\nml) and aliquot of the <1 kDa ultrafiltrate or permeate solutions (10 ml) were\ntransferred into a counting vial for \\u03b3-counting. \n For the binary-sorbent experiments, macromolecular organic matter was added\nafter the inorganic nanoparticles. The experimental solution was then stirred\nfor 30 min to allow inorganic particles to interact with MOCs. After that,\nspikes were added. Other experimental procedures were the same as the single-\nsorbent experiments.\n \nRetentate and permeate samples were measured for 210Pb and 7Be by non-\ndestructive gamma counting using a Canberra ultra-high purity germanium well\ndetector. The counting efficiencies at different sample geometries (1-10 ml)\nat 46.5 keV for 210Pb and 477.6 keV for 7Be were calibrated using tracers with\ncertified activities.\\u00a0\n \nThe activities of 210Po in samples were measured using \\u03b1-spectrometry.\nFor the permeate samples, 5 ml of permeate was acidified to pH <1.5 with HCl,\nthen\\u00a0 4 Bq 209Po was added, followed by ascorbic acid powder, 1 ml of\nhydroxylamine hydrochloride (20%) and 1 ml of sodium citrate (25%).\\u00a0\nFinally, the mixed solution was adjusted to a pH of 1.5. Polonium isotopes,\nincluding 209Po and 210Po, were plated on a silver disc at 90\\u00baC for 4 h\nunder stirring. Procedures for the retentate samples were the same, except\nthat the retentate was digested with mixed acids. Then, the solution was dried\nto near dryness.\\u00a0\n \n\\u00a0Activities of 209Po and 210Po on silver disc were counted by a Canberra\nalpha analyst system. The procedural efficiencies of Po isotopes were\ndetermined by the measured 209Po and initially added 209Po activities. |
attribute | NC_GLOBAL | awards_0_award_nid | String | 735995 |
attribute | NC_GLOBAL | awards_0_award_number | String | OCE-1356453 |
attribute | NC_GLOBAL | awards_0_data_url | String | http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1356453 |
attribute | NC_GLOBAL | awards_0_funder_name | String | NSF Division of Ocean Sciences |
attribute | NC_GLOBAL | awards_0_funding_acronym | String | NSF OCE |
attribute | NC_GLOBAL | awards_0_funding_source_nid | String | 355 |
attribute | NC_GLOBAL | awards_0_program_manager | String | Henrietta N Edmonds |
attribute | NC_GLOBAL | awards_0_program_manager_nid | String | 51517 |
attribute | NC_GLOBAL | cdm_data_type | String | Other |
attribute | NC_GLOBAL | comment | String | Po, Pb and Be partition coefficients on nanoparticles \n PI: Peter Santschi \n Version: 2018-05-14 |
attribute | NC_GLOBAL | Conventions | String | COARDS, CF-1.6, ACDD-1.3 |
attribute | NC_GLOBAL | creator_email | String | info at bco-dmo.org |
attribute | NC_GLOBAL | creator_name | String | BCO-DMO |
attribute | NC_GLOBAL | creator_type | String | institution |
attribute | NC_GLOBAL | creator_url | String | https://www.bco-dmo.org/ |
attribute | NC_GLOBAL | data_source | String | extract_data_as_tsv version 2.3 19 Dec 2019 |
attribute | NC_GLOBAL | date_created | String | 2018-06-15T20:13:12Z |
attribute | NC_GLOBAL | date_modified | String | 2019-09-24T20:07:28Z |
attribute | NC_GLOBAL | defaultDataQuery | String | &time<now |
attribute | NC_GLOBAL | doi | String | 10.1575/1912/bco-dmo.738639.1 |
attribute | NC_GLOBAL | infoUrl | String | https://www.bco-dmo.org/dataset/738639 |
attribute | NC_GLOBAL | institution | String | BCO-DMO |
attribute | NC_GLOBAL | instruments_0_acronym | String | Spectrometer |
attribute | NC_GLOBAL | instruments_0_dataset_instrument_description | String | Alpha-spectrometry, Canberra corporation. |
attribute | NC_GLOBAL | instruments_0_dataset_instrument_nid | String | 738649 |
attribute | NC_GLOBAL | instruments_0_description | String | A spectrometer is an optical instrument used to measure properties of light over a specific portion of the electromagnetic spectrum. |
attribute | NC_GLOBAL | instruments_0_instrument_external_identifier | String | https://vocab.nerc.ac.uk/collection/L22/current/TOOL0460/ |
attribute | NC_GLOBAL | instruments_0_instrument_name | String | Spectrometer |
attribute | NC_GLOBAL | instruments_0_instrument_nid | String | 667 |
attribute | NC_GLOBAL | instruments_0_supplied_name | String | Alpha-spectrometry |
attribute | NC_GLOBAL | instruments_1_dataset_instrument_description | String | Canberra ultra-high purity germanium well detector. |
attribute | NC_GLOBAL | instruments_1_dataset_instrument_nid | String | 738648 |
attribute | NC_GLOBAL | instruments_1_description | String | Instruments measuring the relative levels of electromagnetic radiation of different wavelengths in the gamma-ray waveband. |
attribute | NC_GLOBAL | instruments_1_instrument_name | String | Gamma Ray Spectrometer |
attribute | NC_GLOBAL | instruments_1_instrument_nid | String | 670659 |
attribute | NC_GLOBAL | instruments_1_supplied_name | String | Gamma-spectrometry |
attribute | NC_GLOBAL | keywords | String | bco, bco-dmo, be7, Be7_recovery, berec, biological, chemical, coefficient, data, dataset, dmo, erddap, err_Berec, err_Kc_Be, err_Kc_Pb, err_Kc_Po, err_Pbrec, err_Porec, error, inorganic, Inorganic_nanoparticle, management, nanoparticle, oceanography, office, organic, Organic_nanoparticle, partition, Partition_coefficient_of_210Pb_Kc, Partition_coefficient_of_210Po_Kc, Partition_coefficient_of_7Be_Kc, pb210, Pb210_recovery, pbrec, po210, Po210_recovery, porec, preliminary, recovery, system |
attribute | NC_GLOBAL | license | String | https://www.bco-dmo.org/dataset/738639/license |
attribute | NC_GLOBAL | metadata_source | String | https://www.bco-dmo.org/api/dataset/738639 |
attribute | NC_GLOBAL | param_mapping | String | {'738639': {}} |
attribute | NC_GLOBAL | parameter_source | String | https://www.bco-dmo.org/mapserver/dataset/738639/parameters |
attribute | NC_GLOBAL | people_0_affiliation | String | Texas A&M, Galveston |
attribute | NC_GLOBAL | people_0_affiliation_acronym | String | TAMUG |
attribute | NC_GLOBAL | people_0_person_name | String | Peter Santschi |
attribute | NC_GLOBAL | people_0_person_nid | String | 735998 |
attribute | NC_GLOBAL | people_0_role | String | Principal Investigator |
attribute | NC_GLOBAL | people_0_role_type | String | originator |
attribute | NC_GLOBAL | people_1_affiliation | String | Texas A&M, Galveston |
attribute | NC_GLOBAL | people_1_affiliation_acronym | String | TAMUG |
attribute | NC_GLOBAL | people_1_person_name | String | Antonietta Quigg |
attribute | NC_GLOBAL | people_1_person_nid | String | 736000 |
attribute | NC_GLOBAL | people_1_role | String | Co-Principal Investigator |
attribute | NC_GLOBAL | people_1_role_type | String | originator |
attribute | NC_GLOBAL | people_2_affiliation | String | Texas A&M, Galveston |
attribute | NC_GLOBAL | people_2_affiliation_acronym | String | TAMUG |
attribute | NC_GLOBAL | people_2_person_name | String | Kathleen Schwehr |
attribute | NC_GLOBAL | people_2_person_nid | String | 736002 |
attribute | NC_GLOBAL | people_2_role | String | Co-Principal Investigator |
attribute | NC_GLOBAL | people_2_role_type | String | originator |
attribute | NC_GLOBAL | people_3_affiliation | String | Texas A&M, Galveston |
attribute | NC_GLOBAL | people_3_affiliation_acronym | String | TAMUG |
attribute | NC_GLOBAL | people_3_person_name | String | Chen Xu |
attribute | NC_GLOBAL | people_3_person_nid | String | 736004 |
attribute | NC_GLOBAL | people_3_role | String | Co-Principal Investigator |
attribute | NC_GLOBAL | people_3_role_type | String | originator |
attribute | NC_GLOBAL | people_4_affiliation | String | Woods Hole Oceanographic Institution |
attribute | NC_GLOBAL | people_4_affiliation_acronym | String | WHOI BCO-DMO |
attribute | NC_GLOBAL | people_4_person_name | String | Mathew Biddle |
attribute | NC_GLOBAL | people_4_person_nid | String | 708682 |
attribute | NC_GLOBAL | people_4_role | String | BCO-DMO Data Manager |
attribute | NC_GLOBAL | people_4_role_type | String | related |
attribute | NC_GLOBAL | project | String | Biopolymers for radionuclides |
attribute | NC_GLOBAL | projects_0_acronym | String | Biopolymers for radionuclides |
attribute | NC_GLOBAL | projects_0_description | String | NSF Award Abstract:\nParticle-associated natural radioisotopes are transported to the ocean floor mostly via silica and carbonate ballasted particles, allowing their use as tracers for particle transport. Th(IV), Pa (IV,V), Po(IV), Pb(II) and Be(II) radionuclides are important proxies in oceanographic investigations, used for tracing particle and colloid cycling, estimating export fluxes of particulate organic carbon, tracing air-sea exchange, paleoproductivity, and/or ocean circulation in paleoceanographic studies. Even though tracer approaches are considered routine, there are cases where data interpretation or validity has become controversial, largely due to uncertainties about inorganic proxies and organic carrier molecules. Recent studies showed that cleaned diatom frustules and pure silica particles, sorb natural radionuclides to a much lower extent (by 1-2 orders of magnitude) than whole diatom cells (with or without shells). Phytoplankton that build siliceous or calcareous shells, such as the diatoms and coccolithophores, are assembled via bio-mineralization processes using biopolymers as nanoscale templates. These templates could serve as possible carriers for radionuclides and stable metals.\nIn this project, a research team at the Texas A & M University at Galveston hypothesize that radionuclide sorption is controlled by selective biopolymers that are associated with biogenic opal (diatoms), CaCO3 (coccolithophores) and the attached exopolymeric substances (EPS), rather than to pure mineral phase. To pursue this idea, the major objectives of their research will include separation, identification and molecular-level characterization of the individual biopolymers (e.g., polysaccharides, uronic acids, proteins, hydroquinones, hydroxamate siderophores, etc.) that are responsible for binding different radionuclides (Th, Pa, Pb, Po and Be) attached to cells or in the matrix of biogenic opal or CaCO3 as well as attached EPS mixture, in laboratory grown diatom and coccolithophore cultures. Laboratory-scale radiolabeling experiments will be conducted, and different separation techniques and characterization techniques will be applied.\nIntellectual Merit : It is expected that this study will help elucidate the molecular basis of the templated growth of diatoms and coccoliths, EPS and their role in scavenging natural radionuclides in the ocean, and help resolve debates on the oceanographic tracer applications of different natural radioisotopes (230,234Th, 231Pa, 210Po, 210Pb and 7,10Be). The proposed interdisciplinary research project will require instrumental approaches for molecular-level characterization of these radionuclides associated carrier molecules.\nBroader Impacts: The results of this study will be relevant for understanding biologically mediated ocean scavenging of radionuclides by diatoms and coccoliths which is important for carbon cycling in the ocean, and will contribute to improved interpretation of data obtained by field studies especially through the GEOTRACES program. This new program will enhance training programs at TAMUG for postdocs, graduate and undergraduate students. Lastly, results will be integrated in college courses and out-reach activities at Texas A&M University, including NSF-REU, Sea Camp, Elder Hostel and exhibits at the local science fair and interaction with its after-school program engaging Grade 9-12 students from groups traditionally underrepresented. |
attribute | NC_GLOBAL | projects_0_end_date | String | 2018-02 |
attribute | NC_GLOBAL | projects_0_name | String | Biopolymers as carrier phases for selected natural radionuclides (of Th, Pa, Pb, Po, Be) in diatoms and coccolithophores |
attribute | NC_GLOBAL | projects_0_project_nid | String | 735996 |
attribute | NC_GLOBAL | projects_0_start_date | String | 2014-03 |
attribute | NC_GLOBAL | publisher_name | String | Biological and Chemical Oceanographic Data Management Office (BCO-DMO) |
attribute | NC_GLOBAL | publisher_type | String | institution |
attribute | NC_GLOBAL | sourceUrl | String | (local files) |
attribute | NC_GLOBAL | standard_name_vocabulary | String | CF Standard Name Table v55 |
attribute | NC_GLOBAL | summary | String | Laboratory sorption experiments were carried out to examine the adsorption of 210Po, 210Pb and 7Be and their fractionation on inorganic nanoparticles, including SiO2,CaCO3, Al2O3, TiO2 and Fe2O3, in the presence or absence of macromolecular organic compounds (MOCs) that include humic acids (HA), acid polysaccharides (APS) and proteins (BSA), in natural seawater. |
attribute | NC_GLOBAL | title | String | [Recoveries and partition coefficients] - Po, Pb and Be partition coefficients on nanoparticles from laboratory experiments (Biopolymers as carrier phases for selected natural radionuclides (of Th, Pa, Pb, Po, Be) in diatoms and coccolithophores) |
attribute | NC_GLOBAL | version | String | 1 |
attribute | NC_GLOBAL | xml_source | String | osprey2erddap.update_xml() v1.3 |
variable | System | String | ||
attribute | System | bcodmo_name | String | sample_descrip |
attribute | System | description | String | Type of sorption experiment. |
attribute | System | long_name | String | System |
attribute | System | units | String | unitless |
variable | Organic_nanoparticle | String | ||
attribute | Organic_nanoparticle | bcodmo_name | String | sample_descrip |
attribute | Organic_nanoparticle | description | String | organic nanoparticle in solution. |
attribute | Organic_nanoparticle | long_name | String | Organic Nanoparticle |
attribute | Organic_nanoparticle | units | String | unitless |
variable | Inorganic_nanoparticle | String | ||
attribute | Inorganic_nanoparticle | bcodmo_name | String | sample_descrip |
attribute | Inorganic_nanoparticle | description | String | inorganic nanoparticle in solution. |
attribute | Inorganic_nanoparticle | long_name | String | Inorganic Nanoparticle |
attribute | Inorganic_nanoparticle | units | String | unitless |
variable | Pb210_recovery | byte | ||
attribute | Pb210_recovery | _FillValue | byte | 127 |
attribute | Pb210_recovery | actual_range | byte | 80, 96 |
attribute | Pb210_recovery | bcodmo_name | String | trace_metal_conc |
attribute | Pb210_recovery | description | String | Chemical recovery of 210Pb in percent (%) |
attribute | Pb210_recovery | long_name | String | Pb210 Recovery |
attribute | Pb210_recovery | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | Pb210_recovery | units | String | unitless |
variable | err_Pbrec | byte | ||
attribute | err_Pbrec | _FillValue | byte | 127 |
attribute | err_Pbrec | actual_range | byte | 1, 6 |
attribute | err_Pbrec | bcodmo_name | String | trace_metal_conc |
attribute | err_Pbrec | description | String | Error of chemical recovery of 210Pb in percent (%) |
attribute | err_Pbrec | long_name | String | Err Pbrec |
attribute | err_Pbrec | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | err_Pbrec | units | String | unitless |
variable | Be7_recovery | byte | ||
attribute | Be7_recovery | _FillValue | byte | 127 |
attribute | Be7_recovery | actual_range | byte | 87, 108 |
attribute | Be7_recovery | bcodmo_name | String | trace_metal_conc |
attribute | Be7_recovery | description | String | Chemical recovery of 7Be in percent (%) |
attribute | Be7_recovery | long_name | String | Be7 Recovery |
attribute | Be7_recovery | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | Be7_recovery | units | String | unitless |
variable | err_Berec | byte | ||
attribute | err_Berec | _FillValue | byte | 127 |
attribute | err_Berec | actual_range | byte | 2, 4 |
attribute | err_Berec | bcodmo_name | String | trace_metal_conc |
attribute | err_Berec | description | String | Error of chemical recovery of 7Be in percent (%) |
attribute | err_Berec | long_name | String | Err Berec |
attribute | err_Berec | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | err_Berec | units | String | unitless |
variable | Po210_recovery | byte | ||
attribute | Po210_recovery | _FillValue | byte | 127 |
attribute | Po210_recovery | actual_range | byte | 75, 89 |
attribute | Po210_recovery | bcodmo_name | String | trace_metal_conc |
attribute | Po210_recovery | description | String | Chemical recovery of 210Po in percent (%) |
attribute | Po210_recovery | long_name | String | Po210 Recovery |
attribute | Po210_recovery | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | Po210_recovery | units | String | unitless |
variable | err_Porec | byte | ||
attribute | err_Porec | _FillValue | byte | 127 |
attribute | err_Porec | actual_range | byte | 7, 12 |
attribute | err_Porec | bcodmo_name | String | trace_metal_conc |
attribute | err_Porec | description | String | Error of chemical recovery of 210Po in percent (%) |
attribute | err_Porec | long_name | String | Err Porec |
attribute | err_Porec | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | err_Porec | units | String | unitless |
variable | Partition_coefficient_of_210Pb_Kc | float | ||
attribute | Partition_coefficient_of_210Pb_Kc | _FillValue | float | NaN |
attribute | Partition_coefficient_of_210Pb_Kc | actual_range | float | 0.48, 1555.7 |
attribute | Partition_coefficient_of_210Pb_Kc | bcodmo_name | String | trace_metal_conc |
attribute | Partition_coefficient_of_210Pb_Kc | description | String | The partition coefficient of 210Pb between true solution ( |
attribute | Partition_coefficient_of_210Pb_Kc | long_name | String | Partition Coefficient Of 210 Pb Kc |
attribute | Partition_coefficient_of_210Pb_Kc | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | Partition_coefficient_of_210Pb_Kc | units | String | 10^4 Liters per Kilogram (L/kg) |
variable | err_Kc_Pb | float | ||
attribute | err_Kc_Pb | _FillValue | float | NaN |
attribute | err_Kc_Pb | actual_range | float | 0.04, 148.08 |
attribute | err_Kc_Pb | bcodmo_name | String | trace_metal_conc |
attribute | err_Kc_Pb | description | String | Error of the partition coefficient of 210Pb between true solution ( |
attribute | err_Kc_Pb | long_name | String | Err Kc Pb |
attribute | err_Kc_Pb | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | err_Kc_Pb | units | String | 10^4 Liters per Kilogram (L/kg) |
variable | Partition_coefficient_of_7Be_Kc | float | ||
attribute | Partition_coefficient_of_7Be_Kc | _FillValue | float | NaN |
attribute | Partition_coefficient_of_7Be_Kc | actual_range | float | 0.11, 175.85 |
attribute | Partition_coefficient_of_7Be_Kc | bcodmo_name | String | trace_metal_conc |
attribute | Partition_coefficient_of_7Be_Kc | description | String | The partition coefficient of 7Be between true solution ( |
attribute | Partition_coefficient_of_7Be_Kc | long_name | String | Partition Coefficient Of 7 Be Kc |
attribute | Partition_coefficient_of_7Be_Kc | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | Partition_coefficient_of_7Be_Kc | units | String | 10^4 Liters per Kilogram (L/kg) |
variable | err_Kc_Be | float | ||
attribute | err_Kc_Be | _FillValue | float | NaN |
attribute | err_Kc_Be | actual_range | float | 0.03, 16.8 |
attribute | err_Kc_Be | bcodmo_name | String | trace_metal_conc |
attribute | err_Kc_Be | description | String | Error of the partition coefficient of 7Be between true solution ( |
attribute | err_Kc_Be | long_name | String | Err Kc Be |
attribute | err_Kc_Be | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | err_Kc_Be | units | String | 10^4 Liters per Kilogram (L/kg) |
variable | Partition_coefficient_of_210Po_Kc | float | ||
attribute | Partition_coefficient_of_210Po_Kc | _FillValue | float | NaN |
attribute | Partition_coefficient_of_210Po_Kc | actual_range | float | 0.42, 22.38 |
attribute | Partition_coefficient_of_210Po_Kc | bcodmo_name | String | trace_metal_conc |
attribute | Partition_coefficient_of_210Po_Kc | description | String | The partition coefficient of 210Po between true solution ( |
attribute | Partition_coefficient_of_210Po_Kc | long_name | String | Partition Coefficient Of 210 Po Kc |
attribute | Partition_coefficient_of_210Po_Kc | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | Partition_coefficient_of_210Po_Kc | units | String | 10^4 Liters per Kilogram (L/kg) |
variable | err_Kc_Po | float | ||
attribute | err_Kc_Po | _FillValue | float | NaN |
attribute | err_Kc_Po | actual_range | float | 0.04, 1.51 |
attribute | err_Kc_Po | bcodmo_name | String | trace_metal_conc |
attribute | err_Kc_Po | description | String | Error of the partition coefficient of 210Po between true solution ( |
attribute | err_Kc_Po | long_name | String | Err Kc Po |
attribute | err_Kc_Po | nerc_identifier | String | https://vocab.nerc.ac.uk/collection/P03/current/C035/ |
attribute | err_Kc_Po | units | String | 10^4 Liters per Kilogram (L/kg) |