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All cores were processed within a few hours after collection. The pore waters were first extracted by slicing sediment cores of &lt; 40 centimeters (cm) long and centrifugation of the pore waters under N2 atmosphere to avoid air contamination. Pore waters were then immediately filtered through 0.22-micrometer (um) PSE syringe filters under N2 atmosphere and either analyzed immediately onboard (Fe speciation, orthophosphate, DIC), preserved acidified with hydrochloric acid at 4 degrees Celsius (Cad, Mnd), frozen (ammonium), or preserved at 4 degrees Celsius after addition of HgCl2 (TA) until analysis.  In addition, samples for TA and carbon isotopic analyses were preserved in glass bottles, whereas other samples were preserved in polypropylene containers.

DIC was analyzed by flow injection analysis (Hall and Aller, 1992), orthophosphate, ammonium, and Fe speciation by spectrophotometry (Murphy and Riley, 1962; Strickland and Parsons, 1972; Stookey, 1970), TA by Gran titration (Gran, 1952), the carbon isotopic signature by isotope ratio mass spectrometry (Wang et al, 2018), and Mnd and Cad by ICP-MS (Magette et al., 2025 In preparation).</gco:CharacterString>
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        <gmd:MD_Band>
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            <gco:MemberName>
              <gco:aName>
                <gco:CharacterString>sd_d13C_DIC</gco:CharacterString>
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                <gco:TypeName>
                  <gco:aName>
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            <gco:CharacterString>Sd_d13c_dic</gco:CharacterString>
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        <gmd:MD_Band>
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            <gco:MemberName>
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            <gco:CharacterString>Mnd</gco:CharacterString>
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          <gmd:units xlink:href="https://unitsofmeasure.org/ucum.html#umol&#x2e;l&#x2d;1&#x2e;&#x28;&#x25;7BuM&#x25;7D&#x29;"/>
        </gmd:MD_Band>
      </gmd:dimension>
      <gmd:dimension>
        <gmd:MD_Band>
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                <gco:CharacterString>sd_Mnd</gco:CharacterString>
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              <gco:attributeType>
                <gco:TypeName>
                  <gco:aName>
                    <gco:CharacterString>float</gco:CharacterString>
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              </gco:attributeType>
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            <gco:CharacterString>Sd_mnd</gco:CharacterString>
          </gmd:descriptor>
          <gmd:units xlink:href="https://unitsofmeasure.org/ucum.html#umol&#x2e;l&#x2d;1&#x2e;&#x28;&#x25;7BuM&#x25;7D&#x29;"/>
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        <gmd:MD_Band>
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                <gco:TypeName>
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            <gco:CharacterString>Cad</gco:CharacterString>
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      <gmd:dimension>
        <gmd:MD_Band>
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                <gco:TypeName>
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            <gco:CharacterString>Sd_cad</gco:CharacterString>
          </gmd:descriptor>
          <gmd:units xlink:href="https://unitsofmeasure.org/ucum.html#mmol&#x2e;l&#x2d;1&#x2e;&#x28;&#x25;7BmM&#x25;7D&#x29;"/>
        </gmd:MD_Band>
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      <gmd:dimension>
        <gmd:MD_Band>
          <gmd:sequenceIdentifier>
            <gco:MemberName>
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            <gco:CharacterString>Fe_ii</gco:CharacterString>
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          <gmd:units xlink:href="https://unitsofmeasure.org/ucum.html#umol&#x2e;l&#x2d;1&#x2e;&#x28;&#x25;7BuM&#x25;7D&#x29;"/>
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        <gmd:MD_Band>
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            <gco:CharacterString>Sd_fe_ii</gco:CharacterString>
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        </gmd:MD_Band>
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        <gmd:MD_Band>
          <gmd:sequenceIdentifier>
            <gco:MemberName>
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                <gco:TypeName>
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            <gco:CharacterString>Sd_fed</gco:CharacterString>
          </gmd:descriptor>
          <gmd:units xlink:href="https://unitsofmeasure.org/ucum.html#umol&#x2e;l&#x2d;1&#x2e;&#x28;&#x25;7BuM&#x25;7D&#x29;"/>
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      <gmd:dimension>
        <gmd:MD_Band>
          <gmd:sequenceIdentifier>
            <gco:MemberName>
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                <gco:TypeName>
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          </gmd:sequenceIdentifier>
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            <gco:CharacterString>Fe_iii_d</gco:CharacterString>
          </gmd:descriptor>
          <gmd:units xlink:href="https://unitsofmeasure.org/ucum.html#umol&#x2e;l&#x2d;1&#x2e;&#x28;&#x25;7BuM&#x25;7D&#x29;"/>
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        <gmd:MD_Band>
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            <gco:CharacterString>Sd_fe_iii_d</gco:CharacterString>
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      <gmd:distributor>
        <gmd:MD_Distributor>
          <gmd:distributorContact>
            <gmd:CI_ResponsibleParty>
              <gmd:individualName>
                <gco:CharacterString>Adam Shepherd</gco:CharacterString>
              </gmd:individualName>
              <gmd:organisationName>
                <gco:CharacterString>BCO-DMO</gco:CharacterString>
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                <gmd:CI_Contact>
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                    <gmd:CI_Telephone>
                      <gmd:voice>
                        <gco:CharacterString>508-289-2772</gco:CharacterString>
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                    <gmd:CI_Address>
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                        <gco:CharacterString>266 Woods Hole Rd. MS#36</gco:CharacterString>
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                      <gmd:city>
                        <gco:CharacterString>Woods Hole</gco:CharacterString>
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                        <gco:CharacterString>MA</gco:CharacterString>
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                      <gmd:country>
                        <gco:CharacterString>USA</gco:CharacterString>
                      </gmd:country>
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                        <gco:CharacterString>erddap@bco-dmo.org</gco:CharacterString>
                      </gmd:electronicMailAddress>
                    </gmd:CI_Address>
                  </gmd:address>
                </gmd:CI_Contact>
              </gmd:contactInfo>
              <gmd:role>
                <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#gmd:CI_RoleCode" codeListValue="distributor">distributor</gmd:CI_RoleCode>
              </gmd:role>
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              <gmd:version>
                <gco:CharacterString>DAP/2.0</gco:CharacterString>
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            </gmd:MD_Format>
          </gmd:distributorFormat>
          <gmd:distributorTransferOptions>
            <gmd:MD_DigitalTransferOptions>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_904417_v2.html</gmd:URL>
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                    <gco:CharacterString>Data Subset Form</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>ERDDAP's version of the OPeNDAP .html web page for this dataset. Specify a subset of the dataset and download the data via OPeNDAP or in many different file types.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
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            <gmd:MD_DigitalTransferOptions>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_904417_v2.graph</gmd:URL>
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                    <gco:CharacterString>Make-A-Graph Form</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>ERDDAP's Make-A-Graph .html web page for this dataset. Create an image with a map or graph of a subset of the data.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="mapDigital">mapDigital</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
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      <gmd:maintenanceNote>
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      </gmd:maintenanceNote>
    </gmd:MD_MaintenanceInformation>
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</gmi:MI_Metadata>
