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Dataset Title:  [mz_30_int_from_o2] - Test of potential mass to charge 30 interferences from
O2 (EAGER: Collaborative Research: Detection limit in marine nitrogen
fixation measurements - Constraints of rates from the mesopelagic ocean)
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Institution:  BCO-DMO   (Dataset ID: bcodmo_dataset_778083)
Information:  Summary ? | License ? | ISO 19115 | Metadata | Background (external link) | Files | Make a graph
 
Variable ?   Optional
Constraint #1 ?
Optional
Constraint #2 ?
   Minimum ?
 
   Maximum ?
 
 Sample (unitless) ?          "1"    "CV"
 Time_of_analysis (unitless) ?          "11:55:56"    "NaN"
 m_z_28 (unitless) ?          2.294674E-8    0.2814767477465812
 m_z_29 (unitless) ?          1.727269E-10    0.4483016055663997
 m_z_30 (unitless) ?          4.788455E-12    0.6846958467871429
 m_z_32 (unitless) ?          1.205668E-11    0.27314851061155104
 m_z_40 (unitless) ?          5.9915E-10    0.2542875061786004
 N2_Ar (unitless) ?          0.030372135407174074    38.33405
 ratio_28_29 (unitless) ?          130.6803    132.8498
 ratio_28_30 (unitless) ?          9.092828    4823.516
 atom_pcnt_15n (unitless) ?          0.39471140788488707    10.18249548891134
 Notes (unitless) ?          "Furnace"    "No Furnace"
 
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The Dataset Attribute Structure (.das) for this Dataset

Attributes {
 s {
  Sample {
    String bcodmo_name "unknown";
    String description "sample";
    String long_name "Sample";
    String units "unitless";
  }
  Time_of_analysis {
    String bcodmo_name "unknown";
    String description "time the analysis was conducted in 24 hour format";
    String long_name "Time Of Analysis";
    String units "unitless";
  }
  m_z_28 {
    Float64 _FillValue NaN;
    Float64 actual_range 2.294674e-8, 0.2814767477465812;
    String bcodmo_name "unknown";
    String description "mass-to-charge";
    String long_name "M Z 28";
    String units "unitless";
  }
  m_z_29 {
    Float64 _FillValue NaN;
    Float64 actual_range 1.727269e-10, 0.4483016055663997;
    String bcodmo_name "unknown";
    String description "mass-to-charge";
    String long_name "M Z 29";
    String units "unitless";
  }
  m_z_30 {
    Float64 _FillValue NaN;
    Float64 actual_range 4.788455e-12, 0.6846958467871429;
    String bcodmo_name "unknown";
    String description "mass-to-charge";
    String long_name "M Z 30";
    String units "unitless";
  }
  m_z_32 {
    Float64 _FillValue NaN;
    Float64 actual_range 1.205668e-11, 0.27314851061155104;
    String bcodmo_name "unknown";
    String description "mass-to-charge";
    String long_name "M Z 32";
    String units "unitless";
  }
  m_z_40 {
    Float64 _FillValue NaN;
    Float64 actual_range 5.9915e-10, 0.2542875061786004;
    String bcodmo_name "unknown";
    String description "mass-to-charge";
    String long_name "M Z 40";
    String units "unitless";
  }
  N2_Ar {
    Float64 _FillValue NaN;
    Float64 actual_range 0.030372135407174074, 38.33405;
    String bcodmo_name "unknown";
    String description "N2/Ar ratio";
    String long_name "N2 Ar";
    String units "unitless";
  }
  ratio_28_29 {
    Float32 _FillValue NaN;
    Float32 actual_range 130.6803, 132.8498;
    String bcodmo_name "unknown";
    String description "28/29 ratio";
    String long_name "Ratio 28 29";
    String units "unitless";
  }
  ratio_28_30 {
    Float32 _FillValue NaN;
    Float32 actual_range 9.092828, 4823.516;
    String bcodmo_name "unknown";
    String description "28/30 ratio";
    String long_name "Ratio 28 30";
    String units "unitless";
  }
  atom_pcnt_15n {
    Float64 _FillValue NaN;
    Float64 actual_range 0.39471140788488707, 10.18249548891134;
    String bcodmo_name "unknown";
    String description "15 N atom %";
    String long_name "Atom Pcnt 15n";
    String units "unitless";
  }
  Notes {
    String bcodmo_name "unknown";
    String description "additional comments";
    String long_name "Notes";
    String units "unitless";
  }
 }
  NC_GLOBAL {
    String access_formats ".htmlTable,.csv,.json,.mat,.nc,.tsv";
    String acquisition_description 
"The measurements presented here were conducted with a MIMS and an IRMS each
equipped with high-temperature copper reduction columns to scrub O2 from the
gas stream entering the source. However, samples measured in parallel on the
IRMS and on the MIMS without the O2 scrubbing column yielded similar 15N atom
% values, indicating that any NO+ generated in the respective IRMS and MIMS
sources was insufficient to alter the 15N atom % significantly in the range
pertinent to 15N2 tracer incubations.";
    String awards_0_award_nid "772538";
    String awards_0_award_number "OCE-1732246";
    String awards_0_data_url "http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1732246";
    String awards_0_funder_name "NSF Division of Ocean Sciences";
    String awards_0_funding_acronym "NSF OCE";
    String awards_0_funding_source_nid "355";
    String awards_0_program_manager "Henrietta N Edmonds";
    String awards_0_program_manager_nid "51517";
    String cdm_data_type "Other";
    String comment 
"Test of potential m/z 30 interferences from O2 
  PI: Julie Granger 
  Version: 2019-09-30";
    String Conventions "COARDS, CF-1.6, ACDD-1.3";
    String creator_email "info@bco-dmo.org";
    String creator_name "BCO-DMO";
    String creator_type "institution";
    String creator_url "https://www.bco-dmo.org/";
    String data_source "extract_data_as_tsv version 2.3  19 Dec 2019";
    String date_created "2019-09-30T16:01:58Z";
    String date_modified "2019-10-02T18:50:00Z";
    String defaultDataQuery "&time<now";
    String doi "10.1575/1912/bco-dmo.778083.1";
    String history 
"2024-11-21T12:19:00Z (local files)
2024-11-21T12:19:00Z https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_778083.html";
    String infoUrl "https://www.bco-dmo.org/dataset/778083";
    String institution "BCO-DMO";
    String instruments_0_acronym "IR Mass Spec";
    String instruments_0_dataset_instrument_description "continuous flow Delta V Isotope Ratio Mass Spectrometer (Smith et al. 2015), and continuous flow-GV Isoprime IRMS (Charoenpong et al., 2014)";
    String instruments_0_dataset_instrument_nid "778091";
    String instruments_0_description "The Isotope-ratio Mass Spectrometer is a particular type of mass spectrometer used to measure the relative abundance of isotopes in a given sample (e.g. VG Prism II Isotope Ratio Mass-Spectrometer).";
    String instruments_0_instrument_external_identifier "https://vocab.nerc.ac.uk/collection/L05/current/LAB16/";
    String instruments_0_instrument_name "Isotope-ratio Mass Spectrometer";
    String instruments_0_instrument_nid "469";
    String instruments_0_supplied_name "Isotope Ratio Mass Spectrometer";
    String instruments_1_acronym "MIMS";
    String instruments_1_dataset_instrument_description "Membrane Inlet Mass Spectrometer (Bay Instruments)";
    String instruments_1_dataset_instrument_nid "778090";
    String instruments_1_description "Membrane-introduction mass spectrometry (MIMS) is a method of introducing analytes into the mass spectrometer's vacuum chamber via a semipermeable membrane.";
    String instruments_1_instrument_name "Membrane Inlet Mass Spectrometer";
    String instruments_1_instrument_nid "661606";
    String instruments_1_supplied_name "Membrane Inlet Mass Spectrometer";
    String keywords "15n, analysis, atom, atom_pcnt_15n, bco, bco-dmo, biological, chemical, data, dataset, dmo, erddap, m_z_28, m_z_29, m_z_30, m_z_32, m_z_40, management, N2_Ar, notes, oceanography, office, pcnt, preliminary, ratio, ratio_28_29, ratio_28_30, sample, time, Time_of_analysis";
    String license "https://www.bco-dmo.org/dataset/778083/license";
    String metadata_source "https://www.bco-dmo.org/api/dataset/778083";
    String param_mapping "{'778083': {}}";
    String parameter_source "https://www.bco-dmo.org/mapserver/dataset/778083/parameters";
    String people_0_affiliation "University of Connecticut";
    String people_0_affiliation_acronym "UConn";
    String people_0_person_name "Julie Granger";
    String people_0_person_nid "528937";
    String people_0_role "Principal Investigator";
    String people_0_role_type "originator";
    String people_1_affiliation "University of Massachusetts Dartmouth";
    String people_1_affiliation_acronym "UMass Dartmouth";
    String people_1_person_name "Annie Bourbonnais";
    String people_1_person_nid "778011";
    String people_1_role "Co-Principal Investigator";
    String people_1_role_type "originator";
    String people_2_affiliation "University of Hawaii";
    String people_2_person_name "Samuel Wilson";
    String people_2_person_nid "51733";
    String people_2_role "Co-Principal Investigator";
    String people_2_role_type "originator";
    String people_3_affiliation "Woods Hole Oceanographic Institution";
    String people_3_affiliation_acronym "WHOI BCO-DMO";
    String people_3_person_name "Mathew Biddle";
    String people_3_person_nid "708682";
    String people_3_role "BCO-DMO Data Manager";
    String people_3_role_type "related";
    String project "EAGER NitFix";
    String projects_0_acronym "EAGER NitFix";
    String projects_0_description 
"NSF Award Abstract:
The availability of nitrogen is required to support the growth and production of organisms living in the surface of our global ocean. This element can be scarce. To alleviate this scarcity, a special class of bacteria and archaea, called nitrogen fixers, can derive the nitrogen needed for growth from nitrogen gas. This project would carefully examine one specific method for measuring nitrogen fixation that has been used recently to suggest the occurrence of small amounts of nitrogen fixation in subsurface ocean waters. If these reports are verified, then a revision of our understanding of the marine nitrogen cycle may be needed. The Ocean Carbon and Biogeochemistry program will be used as a platform to develop community consensus for best practices in nitrogen fixation measurements and detection of diversity, activity, and abundances of the organisms responsible. In addition, a session will be organized in a future national/international conference to communicate with the broader scientific community while developing these best practices.
The goal of this study is to conduct a thorough examination of potential experimental and analytical errors inherent to the 15N2-tracer nitrogen fixation method, in tandem with comprehensive molecular measurements, in mesopelagic ocean waters. Samples will be collected and experimental work conducted on a cruise transect in the North Atlantic Ocean, followed by analytical work in the laboratory. The specific aims of this study are to (1) determine the minimum quantifiable rates of 15N2 fixation based on incubations of mesopelagic waters via characterization of sources of experimental and analytical error, and (2) seek evidence of presence and expression of nitrogen fixation genes via comprehensive molecular approaches on corresponding samples. The range of detectable rates and diazotroph activity from the measurements made in this study will be informative for the understanding of the importance of nitrogen fixation in the oceanic nitrogen budget.";
    String projects_0_end_date "2018-10";
    String projects_0_geolocation "North Atlantic Ocean, Pacific Ocean";
    String projects_0_name "EAGER:  Collaborative Research:  Detection limit in marine nitrogen fixation measurements - Constraints of rates from the mesopelagic ocean";
    String projects_0_project_nid "772534";
    String projects_0_start_date "2017-05";
    String publisher_name "Biological and Chemical Oceanographic Data Management Office (BCO-DMO)";
    String publisher_type "institution";
    String sourceUrl "(local files)";
    String standard_name_vocabulary "CF Standard Name Table v55";
    String summary "Molecular oxygen (O2) has been documented to ionize partially to NO+ in mass spectrometer sources, generating a signal that overlaps with that of 15N2 (mass-to-charge of 30). Here, we tested whether O2 needs to be specifically removed from the sample streams of the Membrane Inlet Mass Spectrometer and the Isotope Ratio Mass Spectrometer in order to properly quantitate 15N2 atom% at pertinent concentrations. Sample streams with and without O2 yielded similar signals, suggesting that O2 does not interfere with the 15N2 atom% measurements in the experimental range with the given instruments.";
    String title "[mz_30_int_from_o2] - Test of potential mass to charge 30 interferences from O2 (EAGER:  Collaborative Research:  Detection limit in marine nitrogen fixation measurements - Constraints of rates from the mesopelagic ocean)";
    String version "1";
    String xml_source "osprey2erddap.update_xml() v1.3";
  }
}

 

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