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Dataset Title: | [TA HDPE bottle storage test] - Total alkalinity from an experiment testing the suitability of high-density polyethylene (HDPE) for collection and long- term storage of total alkalinity samples using laboratory-manipulated oligotrophic Atlantic surface water (US GEOTRACES GP17-OCE and GP17-ANT: Inorganic Carbon Cycling in the South Pacific and Southern Oceans by Direct Measurement) ![]() ![]() |
Institution: | BCO-DMO (Dataset ID: bcodmo_dataset_957694_v1) |
Information: | Summary ![]() ![]() ![]() |
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Attributes { s { Bottle_ID { String long_name "Bottle_id"; String units "unitless"; } Soak_solution { String long_name "Soak_solution"; String units "unitless"; } Soak_Duration { Int32 actual_range 0, 2; String long_name "Soak_duration"; String units "weeks"; } Bottle_Number { Int32 actual_range 1, 23; String long_name "Bottle_number"; String units "unitless"; } Analysis_Date_Time_EST { String long_name "Analysis_date_time_est"; String units "unitless"; } Total_Alkalinity { Float32 actual_range 2213.75, 2358.58; String long_name "Total_alkalinity"; String units "micromoles per kilogram seawater (umol/kg_sw)"; } Analysis_Flag { Int32 actual_range 2, 5; String long_name "Analysis_flag"; String units "unitless"; } } NC_GLOBAL { String cdm_data_type "Other"; String Conventions "COARDS, CF-1.6, ACDD-1.3"; String creator_email "info@bco-dmo.org"; String creator_name "BCO-DMO"; String creator_url "https://www.bco-dmo.org/"; String doi "10.26008/1912/bco-dmo.957694.1"; String history "2025-05-12T09:29:08Z (local files) 2025-05-12T09:29:08Z https://erddap.bco-dmo.org/tabledap/bcodmo_dataset_957694_v1.das"; String infoUrl "https://osprey.bco-dmo.org/dataset/957694"; String institution "BCO-DMO"; String license "The data may be used and redistributed for free but is not intended for legal use, since it may contain inaccuracies. Neither the data Contributor, ERD, NOAA, nor the United States Government, nor any of their employees or contractors, makes any warranty, express or implied, including warranties of merchantability and fitness for a particular purpose, or assumes any legal liability for the accuracy, completeness, or usefulness, of this information."; String sourceUrl "(local files)"; String summary "Total alkalinity plays an important role in buffering seawater and determining how much anthropogenic carbon dioxide the oceans can absorb and mitigate the rise in atmospheric concentrations. Total alkalinity varies with location, depth, and time making it an important variable needed to quantify and monitor ocean acidification, and potentially for ocean alkalinity enhancement interventions. Currently, best practices are to use expensive high quality borosilicate glass bottles for collecting and storing these samples. However, unlike other carbon system variables, total alkalinity is not affected by gas exchange meaning plastic bottles may be suitable for total alkalinity sample storage. Plastic bottles are lighter, cheaper, and less prone to breakage making them easier to handle and ship. Here, we test the suitability of high-density polyethylene (HDPE) for collection and long-term storage of total alkalinity samples through laboratory experiments where HDPE bottles were treated to different cleaning methods and then filled with surface seawater and stored for 15-17 months before analyzing for total alkalinity. It was determined that HDPE is not suitable for long-term storage of total alkalinity samples as there were large changes in total alkalinity over time and precision of duplicate samples was very poor. We hypothesize that HDPE plastic is slightly porous leading to leaching of alkalinity either into or out of the bottle over time impacting the value of the sample. Use of HDPE bottles for total alkalinity samples is not recommended for long term sample storage."; String title "[TA HDPE bottle storage test] - Total alkalinity from an experiment testing the suitability of high-density polyethylene (HDPE) for collection and long-term storage of total alkalinity samples using laboratory-manipulated oligotrophic Atlantic surface water (US GEOTRACES GP17-OCE and GP17-ANT: Inorganic Carbon Cycling in the South Pacific and Southern Oceans by Direct Measurement)"; } }
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