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| Grid DAP Data | Sub- set | Table DAP Data | Make A Graph | W M S | Source Data Files | Acces- sible
| Title | Sum- mary | FGDC, ISO, Metadata | Back- ground Info | RSS | E | Institution | Dataset ID |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| data | graph | files | public | [Boric acid dissociation constants in freshwater and marine conditions] - Boric acid dissociation constants (pKB) from spectrophotometrically calibrated electrode measurements made in natural seawater across estuarine to open-ocean conditions (Spectrophotometric Determinations of Carbonic Acid Dissociation Constants for Estuarine Conditions) |
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| BCO-DMO | bcodmo_dataset_1000973_v1 |
| Row Type | Variable Name | Attribute Name | Data Type | Value |
|---|---|---|---|---|
| attribute | NC_GLOBAL | cdm_data_type | String | Other |
| attribute | NC_GLOBAL | Conventions | String | COARDS, CF-1.6, ACDD-1.3 |
| attribute | NC_GLOBAL | creator_email | String | info at bco-dmo.org |
| attribute | NC_GLOBAL | creator_name | String | BCO-DMO |
| attribute | NC_GLOBAL | creator_url | String | https://www.bco-dmo.org/![]() |
| attribute | NC_GLOBAL | doi | String | 10.26008/1912/bco-dmo.1000973.1 |
| attribute | NC_GLOBAL | infoUrl | String | https://osprey.bco-dmo.org/dataset/1000973![]() |
| attribute | NC_GLOBAL | institution | String | BCO-DMO |
| attribute | NC_GLOBAL | license | String | The data may be used and redistributed for free but is not intended for legal use, since it may contain inaccuracies. Neither the data Contributor, ERD, NOAA, nor the United States Government, nor any of their employees or contractors, makes any warranty, express or implied, including warranties of merchantability and fitness for a particular purpose, or assumes any legal liability for the accuracy, completeness, or usefulness, of this information. |
| attribute | NC_GLOBAL | sourceUrl | String | (local files) |
| attribute | NC_GLOBAL | summary | String | The dissociation constant of boric acid (KB) plays a critical role in marine carbonate system calculations, yet available parameterizations remain limited in salinity coverage and have not been revisited using modern methodology. This dataset combines Dickson (1990)'s data (i.e., D90) in synthetic seawater with our own work (i.e., MMB26) to produce an improved parameterization of pKB for carbonate system calculations across a full range of estuarine and open-ocean environments. MMB26 is a novel dataset of pKB obtained in natural seawater, derived from spectrophotometrically calibrated electrode measurements spanning salinities from 0 to 45.9 and temperatures between 275.15 and 308.15 K. This experimental data is particularly important given that nearly half the total variation in pKB across the full salinity range occurs within the narrow freshwater-to-brackish transition. The spectrophotometrically calibrated electrode data (MMB26) are in excellent agreement with previous work obtained in synthetic seawater at salinities greater than 5 (D90). |
| attribute | NC_GLOBAL | title | String | [Boric acid dissociation constants in freshwater and marine conditions] - Boric acid dissociation constants (pKB) from spectrophotometrically calibrated electrode measurements made in natural seawater across estuarine to open-ocean conditions (Spectrophotometric Determinations of Carbonic Acid Dissociation Constants for Estuarine Conditions) |
| variable | source | String | ||
| attribute | source | long_name | String | Source |
| attribute | source | units | String | unitless |
| variable | Target_t_C | int | ||
| attribute | Target_t_C | actual_range | int | 0, 45 |
| attribute | Target_t_C | long_name | String | Target_t_c |
| attribute | Target_t_C | units | String | degrees Celsius (°C) |
| variable | Target_T_K | float | ||
| attribute | Target_T_K | actual_range | float | 273.15, 318.15 |
| attribute | Target_T_K | long_name | String | Target_t_k |
| attribute | Target_T_K | units | String | Kelvin (K) |
| variable | Target_Sal | float | ||
| attribute | Target_Sal | actual_range | float | 0.0, 45.0 |
| attribute | Target_Sal | long_name | String | Target_sal |
| attribute | Target_Sal | units | String | PSS-78 |
| variable | Temp_C | float | ||
| attribute | Temp_C | actual_range | float | 0.0, 45.0 |
| attribute | Temp_C | long_name | String | Temp_c |
| attribute | Temp_C | units | String | degrees Celsius (°C) |
| variable | Temp_K | float | ||
| attribute | Temp_K | actual_range | float | 273.15, 318.15 |
| attribute | Temp_K | long_name | String | Temp_k |
| attribute | Temp_K | units | String | Kelvin (K) |
| variable | Sal | float | ||
| attribute | Sal | actual_range | float | 0.0, 45.865 |
| attribute | Sal | long_name | String | Sal |
| attribute | Sal | units | String | PSS-78 |
| variable | exp_pKB_combined | float | ||
| attribute | exp_pKB_combined | actual_range | float | 8.3151, 9.4763 |
| attribute | exp_pKB_combined | long_name | String | Exp_pkb_combined |
| attribute | exp_pKB_combined | units | String | unitless |
| variable | borax_added_mg | float | ||
| attribute | borax_added_mg | actual_range | float | 76.5, 139.1 |
| attribute | borax_added_mg | long_name | String | Borax_added_mg |
| attribute | borax_added_mg | units | String | milligrams (mg) |
| variable | sw_origin | String | ||
| attribute | sw_origin | long_name | String | Sw_origin |
| attribute | sw_origin | units | String | unitless |
| variable | sw_collection_year | String | ||
| attribute | sw_collection_year | long_name | String | Sw_collection_year |
| attribute | sw_collection_year | units | String | unitless |
The information in the table above is also available in other file formats (.csv, .htmlTable, .itx, .json, .jsonlCSV1, .jsonlCSV, .jsonlKVP, .mat, .nc, .nccsv, .tsv, .xhtml) via a RESTful web service.