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     data   graph     files  public [Boric acid dissociation constants in freshwater and marine conditions] - Boric acid
dissociation constants (pKB) from spectrophotometrically calibrated electrode measurements
made in natural seawater across estuarine to open-ocean conditions (Spectrophotometric
Determinations of Carbonic Acid Dissociation Constants for Estuarine Conditions)
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The Dataset's Variables and Attributes

Row Type Variable Name Attribute Name Data Type Value
attribute NC_GLOBAL cdm_data_type String Other
attribute NC_GLOBAL Conventions String COARDS, CF-1.6, ACDD-1.3
attribute NC_GLOBAL creator_email String info at bco-dmo.org
attribute NC_GLOBAL creator_name String BCO-DMO
attribute NC_GLOBAL creator_url String https://www.bco-dmo.org/ (external link)
attribute NC_GLOBAL doi String 10.26008/1912/bco-dmo.1000973.1
attribute NC_GLOBAL infoUrl String https://osprey.bco-dmo.org/dataset/1000973 (external link)
attribute NC_GLOBAL institution String BCO-DMO
attribute NC_GLOBAL license String The data may be used and redistributed for free but is not intended
for legal use, since it may contain inaccuracies. Neither the data
Contributor, ERD, NOAA, nor the United States Government, nor any
of their employees or contractors, makes any warranty, express or
implied, including warranties of merchantability and fitness for a
particular purpose, or assumes any legal liability for the accuracy,
completeness, or usefulness, of this information.
attribute NC_GLOBAL sourceUrl String (local files)
attribute NC_GLOBAL summary String The dissociation constant of boric acid (KB) plays a critical role in marine carbonate system calculations, yet available parameterizations remain limited in salinity coverage and have not been revisited using modern methodology. This dataset combines Dickson (1990)'s data (i.e., D90) in synthetic seawater with our own work (i.e., MMB26) to produce an improved parameterization of pKB for carbonate system calculations across a full range of estuarine and open-ocean environments. MMB26 is a novel dataset of pKB obtained in natural seawater, derived from spectrophotometrically calibrated electrode measurements spanning salinities from 0 to 45.9 and temperatures between 275.15 and 308.15 K. This experimental data is particularly important given that nearly half the total variation in pKB across the full salinity range occurs within the narrow freshwater-to-brackish transition. The spectrophotometrically calibrated electrode data (MMB26) are in excellent agreement with previous work obtained in synthetic seawater at salinities greater than 5 (D90).
attribute NC_GLOBAL title String [Boric acid dissociation constants in freshwater and marine conditions] - Boric acid dissociation constants (pKB) from spectrophotometrically calibrated electrode measurements made in natural seawater across estuarine to open-ocean conditions (Spectrophotometric Determinations of Carbonic Acid Dissociation Constants for Estuarine Conditions)
variable source   String  
attribute source long_name String Source
attribute source units String unitless
variable Target_t_C   int  
attribute Target_t_C actual_range int 0, 45
attribute Target_t_C long_name String Target_t_c
attribute Target_t_C units String degrees Celsius (°C)
variable Target_T_K   float  
attribute Target_T_K actual_range float 273.15, 318.15
attribute Target_T_K long_name String Target_t_k
attribute Target_T_K units String Kelvin (K)
variable Target_Sal   float  
attribute Target_Sal actual_range float 0.0, 45.0
attribute Target_Sal long_name String Target_sal
attribute Target_Sal units String PSS-78
variable Temp_C   float  
attribute Temp_C actual_range float 0.0, 45.0
attribute Temp_C long_name String Temp_c
attribute Temp_C units String degrees Celsius (°C)
variable Temp_K   float  
attribute Temp_K actual_range float 273.15, 318.15
attribute Temp_K long_name String Temp_k
attribute Temp_K units String Kelvin (K)
variable Sal   float  
attribute Sal actual_range float 0.0, 45.865
attribute Sal long_name String Sal
attribute Sal units String PSS-78
variable exp_pKB_combined   float  
attribute exp_pKB_combined actual_range float 8.3151, 9.4763
attribute exp_pKB_combined long_name String Exp_pkb_combined
attribute exp_pKB_combined units String unitless
variable borax_added_mg   float  
attribute borax_added_mg actual_range float 76.5, 139.1
attribute borax_added_mg long_name String Borax_added_mg
attribute borax_added_mg units String milligrams (mg)
variable sw_origin   String  
attribute sw_origin long_name String Sw_origin
attribute sw_origin units String unitless
variable sw_collection_year   String  
attribute sw_collection_year long_name String Sw_collection_year
attribute sw_collection_year units String unitless

The information in the table above is also available in other file formats (.csv, .htmlTable, .itx, .json, .jsonlCSV1, .jsonlCSV, .jsonlKVP, .mat, .nc, .nccsv, .tsv, .xhtml) via a RESTful web service.


 
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