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     data   graph     files  public [Sulfur NEXFS Standards] - Sulfur Near Edge X-ray Fluorescence Spectroscopy Data for standard
materials (P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean
Sea)
   ?        I   M   background (external link) RSS Subscribe BCO-DMO bcodmo_dataset_756682

The Dataset's Variables and Attributes

Row Type Variable Name Attribute Name Data Type Value
attribute NC_GLOBAL access_formats String .htmlTable,.csv,.json,.mat,.nc,.tsv
attribute NC_GLOBAL acquisition_description String Methodology: The sulfur standards were ground using an agate mortar and pestle
to the consistency of a fine talcum powder (approximately 10 um). A cellulose
acetate filter was then gently dredged through a small quantity (less than 1
mg) of powder placed on a microscope slide. This procedure produced a thin and
almost imperceptible coating on the filter in order to limit the thickness and
thus self-absorption. S-NEXFS spectra of sulfate standards were collected in
bulk mode. Self-absorption must be carefully controlled when measuring
fluorescent X-rays from thick specimens; however, the effects of self-
absorption are limited to the region of the spectrum above the K-edge. In our
repeated measurements, the post-edge features were consistent and
reproducible, which allows discrimination of different sulfate standards.

Sampling and analytical procedures: S compounds and minerals were obtained
from chemical supply houses or mineral dealers. See papers cited below for
details.

Instruments: X-ray fluorescence microscope located at beamline 2-ID-B at the
Advanced Photon Source, Argonne National Laboratory. The beamline is optimized
to examine samples over a 1\u20134 keV energy range using a focused X-ray beam
with a spot size of approximately 60 nanometers squared . The energy was
calibrated using an elemental sulfur standard. The whiteline energy of the
elemental sulfur standard was aligned to 2472 eV.

Data processing: S-NEXFS data were normalized to create a relative intensity
value of approximately 1 for post-edge area of the spectra. The data were also
processed using a three-point smoothing algorithm built into the software
package Athena to remove high-frequency noise (Ravel and Newville, 2005).
attribute NC_GLOBAL awards_0_award_nid String 753301
attribute NC_GLOBAL awards_0_award_number String OCE-1357375
attribute NC_GLOBAL awards_0_data_url String http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1357375 (external link)
attribute NC_GLOBAL awards_0_funder_name String NSF Division of Ocean Sciences
attribute NC_GLOBAL awards_0_funding_acronym String NSF OCE
attribute NC_GLOBAL awards_0_funding_source_nid String 355
attribute NC_GLOBAL awards_0_program_manager String Henrietta N Edmonds
attribute NC_GLOBAL awards_0_program_manager_nid String 51517
attribute NC_GLOBAL cdm_data_type String Other
attribute NC_GLOBAL comment String Sulfur NEXFS Standards
PI: Ellery Ingall (GA Tech)
Version date: 22-Feb-2019
attribute NC_GLOBAL Conventions String COARDS, CF-1.6, ACDD-1.3
attribute NC_GLOBAL creator_email String info at bco-dmo.org
attribute NC_GLOBAL creator_name String BCO-DMO
attribute NC_GLOBAL creator_type String institution
attribute NC_GLOBAL creator_url String https://www.bco-dmo.org/ (external link)
attribute NC_GLOBAL data_source String extract_data_as_tsv version 2.3 19 Dec 2019
attribute NC_GLOBAL date_created String 2019-02-22T17:35:30Z
attribute NC_GLOBAL date_modified String 2019-03-29T19:26:39Z
attribute NC_GLOBAL defaultDataQuery String &time<now
attribute NC_GLOBAL doi String 10.1575/1912/bco-dmo.756682.1
attribute NC_GLOBAL infoUrl String https://www.bco-dmo.org/dataset/756682 (external link)
attribute NC_GLOBAL institution String BCO-DMO
attribute NC_GLOBAL instruments_0_dataset_instrument_description String X-ray fluorescence microscope located at beamline 2-ID-B at the Advanced Photon Source, Argonne National Laboratory: The beamline is optimized to examine samples over a 1–4 keV energy range using a focused X-ray beam with a spot size of approximately 60 nanometers squared . The energy was calibrated using an elemental sulfur standard. The whiteline energy of the elemental sulfur standard was aligned to 2472 eV.
attribute NC_GLOBAL instruments_0_dataset_instrument_nid String 756694
attribute NC_GLOBAL instruments_0_description String Instruments that generate enlarged images of samples using the phenomena of fluorescence and phosphorescence instead of, or in addition to, reflection and absorption of visible light. Includes conventional and inverted instruments.
attribute NC_GLOBAL instruments_0_instrument_external_identifier String https://vocab.nerc.ac.uk/collection/L05/current/LAB06/ (external link)
attribute NC_GLOBAL instruments_0_instrument_name String Microscope-Fluorescence
attribute NC_GLOBAL instruments_0_instrument_nid String 695
attribute NC_GLOBAL instruments_0_supplied_name String X-ray fluorescence microscope
attribute NC_GLOBAL keywords String ammonia, ammonium, Ammonium_Sulfate, barite, bco, bco-dmo, biological, chemical, chemistry, concentration, copper, Copper_II_Sulfate, data, dataset, dmo, earth, Earth Science > Oceans > Ocean Chemistry > Ammonia, energy, erddap, gypsum, iii, iron, Iron_Ammonium_Sulfate, Iron_III_Sulfate, jarosite, magnesium, Magnesium_Sulfate, management, mole, mole_concentration_of_ammonium_in_sea_water, nh4, ocean, oceanography, oceans, office, potassium, Potassium_Sulfate, preliminary, science, sea, seawater, sodium, Sodium_Sulfate, sulfate, water
attribute NC_GLOBAL keywords_vocabulary String GCMD Science Keywords
attribute NC_GLOBAL license String https://www.bco-dmo.org/dataset/756682/license (external link)
attribute NC_GLOBAL metadata_source String https://www.bco-dmo.org/api/dataset/756682 (external link)
attribute NC_GLOBAL param_mapping String {'756682': {}}
attribute NC_GLOBAL parameter_source String https://www.bco-dmo.org/mapserver/dataset/756682/parameters (external link)
attribute NC_GLOBAL people_0_affiliation String Georgia Institute of Technology
attribute NC_GLOBAL people_0_affiliation_acronym String Georgia Tech
attribute NC_GLOBAL people_0_person_name String Ellery Ingall
attribute NC_GLOBAL people_0_person_nid String 645498
attribute NC_GLOBAL people_0_role String Principal Investigator
attribute NC_GLOBAL people_0_role_type String originator
attribute NC_GLOBAL people_1_affiliation String Woods Hole Oceanographic Institution
attribute NC_GLOBAL people_1_affiliation_acronym String WHOI BCO-DMO
attribute NC_GLOBAL people_1_person_name String Shannon Rauch
attribute NC_GLOBAL people_1_person_nid String 51498
attribute NC_GLOBAL people_1_role String BCO-DMO Data Manager
attribute NC_GLOBAL people_1_role_type String related
attribute NC_GLOBAL project String Aerosol P
attribute NC_GLOBAL projects_0_acronym String Aerosol P
attribute NC_GLOBAL projects_0_description String NSF Award Abstract:
Primary nutrients, such as nitrogen and phosphorus, are critical for all life on earth, and limited quantities in the marine environment can inhibit primary productivity. Atmospheric aerosols are a significant source of these nutrients to nutrient-poor ocean regions, such as the phosphorus-limited Mediterranean Sea. The availability of phosphorus in aerosols has traditionally been linked to the composition and abundance of different phosphorus phases present. Unfortunately, investigating phosphorus composition in aerosols has been challenging due to methodological limitations until recently. In this study, researchers from Georgia Tech will use a new technique known as synchrotron-based P Near Edge X-ray Fluorescence Spectroscopy, in conjunction with X-ray fluorescence microscopy, to examine the diversity of aerosol phosphorus phases delivered to the Mediterranean Sea. By defining the relationship between air mass source region, aerosol composition, and bioavailability, results from this work will improve current knowledge of the factors regulating productivity in the Mediterranean Sea and help to clarify the potential response of this region to different climate change scenarios.
Broader Impacts: In addition to the valuable insights this project will provide on the controls on productivity and nutrient cycling in the Mediterranean Sea, this study will further education of young scientists, broaden participation of under-represented groups in ocean science, and enhance research infrastructure.
attribute NC_GLOBAL projects_0_end_date String 2018-07
attribute NC_GLOBAL projects_0_geolocation String Mediterranean
attribute NC_GLOBAL projects_0_name String P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea
attribute NC_GLOBAL projects_0_project_nid String 753302
attribute NC_GLOBAL projects_0_start_date String 2014-02
attribute NC_GLOBAL publisher_name String Biological and Chemical Oceanographic Data Management Office (BCO-DMO)
attribute NC_GLOBAL publisher_type String institution
attribute NC_GLOBAL sourceUrl String (local files)
attribute NC_GLOBAL standard_name_vocabulary String CF Standard Name Table v55
attribute NC_GLOBAL summary String Sulfur Near Edge X-ray Fluorescence Spectroscopy Data for standard materials.
attribute NC_GLOBAL title String [Sulfur NEXFS Standards] - Sulfur Near Edge X-ray Fluorescence Spectroscopy Data for standard materials (P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea)
attribute NC_GLOBAL version String 1
attribute NC_GLOBAL xml_source String osprey2erddap.update_xml() v1.3
variable Energy   double  
attribute Energy _FillValue double NaN
attribute Energy actual_range double 2462.95, 2512.95
attribute Energy bcodmo_name String unknown
attribute Energy description String X-ray energy
attribute Energy long_name String Energy
attribute Energy units String electron volts
variable Ammonium_Sulfate   double  
attribute Ammonium_Sulfate _FillValue double NaN
attribute Ammonium_Sulfate actual_range double -0.00651, 2.9953469
attribute Ammonium_Sulfate bcodmo_name String count
attribute Ammonium_Sulfate colorBarMaximum double 5.0
attribute Ammonium_Sulfate colorBarMinimum double 0.0
attribute Ammonium_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Ammonium_Sulfate long_name String Mole Concentration Of Ammonium In Sea Water
attribute Ammonium_Sulfate units String x-ray fluorescence counts
variable Barite   double  
attribute Barite _FillValue double NaN
attribute Barite actual_range double -0.00205, 1.4496355
attribute Barite bcodmo_name String count
attribute Barite description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Barite long_name String Barite
attribute Barite units String x-ray fluorescence counts
variable Copper_II_Sulfate   double  
attribute Copper_II_Sulfate _FillValue double NaN
attribute Copper_II_Sulfate actual_range double -0.00241, 1.8524978
attribute Copper_II_Sulfate bcodmo_name String count
attribute Copper_II_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Copper_II_Sulfate long_name String Copper II Sulfate
attribute Copper_II_Sulfate units String x-ray fluorescence counts
variable Gypsum   double  
attribute Gypsum _FillValue double NaN
attribute Gypsum actual_range double -0.00256, 2.0457804
attribute Gypsum bcodmo_name String count
attribute Gypsum description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Gypsum long_name String Gypsum
attribute Gypsum units String x-ray fluorescence counts
variable Iron_Ammonium_Sulfate   double  
attribute Iron_Ammonium_Sulfate _FillValue double NaN
attribute Iron_Ammonium_Sulfate actual_range double -0.0229, 1.6765362
attribute Iron_Ammonium_Sulfate bcodmo_name String count
attribute Iron_Ammonium_Sulfate colorBarMaximum double 5.0
attribute Iron_Ammonium_Sulfate colorBarMinimum double 0.0
attribute Iron_Ammonium_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Iron_Ammonium_Sulfate long_name String Mole Concentration Of Ammonium In Sea Water
attribute Iron_Ammonium_Sulfate units String x-ray fluorescence counts
variable Iron_III_Sulfate   double  
attribute Iron_III_Sulfate _FillValue double NaN
attribute Iron_III_Sulfate actual_range double -0.00876, 2.6487011
attribute Iron_III_Sulfate bcodmo_name String count
attribute Iron_III_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Iron_III_Sulfate long_name String Iron III Sulfate
attribute Iron_III_Sulfate units String x-ray fluorescence counts
variable Jarosite   double  
attribute Jarosite _FillValue double NaN
attribute Jarosite actual_range double -0.00578, 2.1202962
attribute Jarosite bcodmo_name String count
attribute Jarosite description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Jarosite long_name String Jarosite
attribute Jarosite units String x-ray fluorescence counts
variable Magnesium_Sulfate   double  
attribute Magnesium_Sulfate _FillValue double NaN
attribute Magnesium_Sulfate actual_range double -0.00785, 1.6286722
attribute Magnesium_Sulfate bcodmo_name String count
attribute Magnesium_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Magnesium_Sulfate long_name String Magnesium Sulfate
attribute Magnesium_Sulfate units String x-ray fluorescence counts
variable Potassium_Sulfate   double  
attribute Potassium_Sulfate _FillValue double NaN
attribute Potassium_Sulfate actual_range double -0.00713, 1.5300749
attribute Potassium_Sulfate bcodmo_name String count
attribute Potassium_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Potassium_Sulfate long_name String Potassium Sulfate
attribute Potassium_Sulfate units String x-ray fluorescence counts
variable Sodium_Sulfate   double  
attribute Sodium_Sulfate _FillValue double NaN
attribute Sodium_Sulfate actual_range double -0.0139, 2.0601661
attribute Sodium_Sulfate bcodmo_name String count
attribute Sodium_Sulfate description String Name of sulfur standard or mineral analyzed. Units (x-ray fluorescence counts) are normalized to incoming radiation.
attribute Sodium_Sulfate long_name String Sodium Sulfate
attribute Sodium_Sulfate units String x-ray fluorescence counts

The information in the table above is also available in other file formats (.csv, .htmlTable, .itx, .json, .jsonlCSV1, .jsonlCSV, .jsonlKVP, .mat, .nc, .nccsv, .tsv, .xhtml) via a RESTful web service.


 
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