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     data   graph     files  public [TA HDPE glass bottle comparison] - Total alkalinity determined through experiments comparing
usage of high-density polyethylene (HDPE) and borosilicate glass bottles for collection and
storage of water samples collected on the GEOTRACES GP17-OCE cruise (R/V Roger Revelle
RR2214) (US GEOTRACES GP17-OCE and GP17-ANT: Inorganic Carbon Cycling in the South Pacific and
Southern Oceans by Direct Measurement)
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The Dataset's Variables and Attributes

Row Type Variable Name Attribute Name Data Type Value
attribute NC_GLOBAL cdm_data_type String Other
attribute NC_GLOBAL Conventions String COARDS, CF-1.6, ACDD-1.3
attribute NC_GLOBAL creator_email String info at bco-dmo.org
attribute NC_GLOBAL creator_name String BCO-DMO
attribute NC_GLOBAL creator_url String https://www.bco-dmo.org/ (external link)
attribute NC_GLOBAL defaultDataQuery String &time<now
attribute NC_GLOBAL doi String 10.26008/1912/bco-dmo.957644.1
attribute NC_GLOBAL Easternmost_Easting double -75.09732
attribute NC_GLOBAL geospatial_lat_max double -19.99984
attribute NC_GLOBAL geospatial_lat_min double -67.00024
attribute NC_GLOBAL geospatial_lat_units String degrees_north
attribute NC_GLOBAL geospatial_lon_max double -75.09732
attribute NC_GLOBAL geospatial_lon_min double -152.0003
attribute NC_GLOBAL geospatial_lon_units String degrees_east
attribute NC_GLOBAL infoUrl String https://osprey.bco-dmo.org/dataset/957644 (external link)
attribute NC_GLOBAL institution String BCO-DMO
attribute NC_GLOBAL license String The data may be used and redistributed for free but is not intended
for legal use, since it may contain inaccuracies. Neither the data
Contributor, ERD, NOAA, nor the United States Government, nor any
of their employees or contractors, makes any warranty, express or
implied, including warranties of merchantability and fitness for a
particular purpose, or assumes any legal liability for the accuracy,
completeness, or usefulness, of this information.
attribute NC_GLOBAL Northernmost_Northing double -19.99984
attribute NC_GLOBAL sourceUrl String (local files)
attribute NC_GLOBAL Southernmost_Northing double -67.00024
attribute NC_GLOBAL summary String Total alkalinity plays an important role in buffering seawater and determining how much anthropogenic carbon dioxide the oceans can absorb and mitigate the rise in atmospheric concentrations. Total alkalinity varies with location, depth, and time making it an important variable needed to quantify and monitor ocean acidification, and potentially for ocean alkalinity enhancement interventions. Currently, best practices are to use expensive high quality borosilicate glass bottles for collecting and storing these samples. However, unlike other carbon system variables, total alkalinity is not affected by gas exchange meaning plastic bottles may be suitable for total alkalinity sample storage. Plastic bottles are lighter, cheaper, and less prone to breakage making them easier to handle and ship. Here, we test the suitability of high-density polyethylene (HDPE) for collection and long-term storage of total alkalinity samples. Duplicate samples were collected in standard borosilicate glass bottles and HDPE bottles on GEOTRACES GP17-OCE. The samples were analyzed in the laboratory over a year later and the storage methods were compared. It was determined that HDPE is not suitable for long-term storage of total alkalinity samples as there were large changes in total alkalinity over time and precision of duplicate samples was very poor. We hypothesize that HDPE plastic is slightly porous leading to leaching of alkalinity either into or out of the bottle over time impacting the value of the sample. Use of HDPE bottles for total alkalinity samples is not recommended for long term sample storage.
attribute NC_GLOBAL time_coverage_end String 2023-01-24T03:21:00Z
attribute NC_GLOBAL time_coverage_start String 2022-12-04T00:38:00Z
attribute NC_GLOBAL title String [TA HDPE glass bottle comparison] - Total alkalinity determined through experiments comparing usage of high-density polyethylene (HDPE) and borosilicate glass bottles for collection and storage of water samples collected on the GEOTRACES GP17-OCE cruise (R/V Roger Revelle RR2214) (US GEOTRACES GP17-OCE and GP17-ANT: Inorganic Carbon Cycling in the South Pacific and Southern Oceans by Direct Measurement)
attribute NC_GLOBAL Westernmost_Easting double -152.0003
variable GEOTRACES_sample   int  
attribute GEOTRACES_sample actual_range int 15907, 18755
attribute GEOTRACES_sample long_name String Geotraces_sample
attribute GEOTRACES_sample units String unitless
variable Event_number   String  
attribute Event_number long_name String Event_number
attribute Event_number units String unitless
variable Date   String  
attribute Date long_name String Date
attribute Date units String unitless
variable time_unitless   String  
attribute time_unitless long_name String Time
attribute time_unitless units String unitless
variable time   double  
attribute time _CoordinateAxisType String Time
attribute time actual_range double 1.67011428E9, 1.67453046E9
attribute time axis String T
attribute time ioos_category String Time
attribute time long_name String Iso_datetime_utc
attribute time standard_name String time
attribute time time_origin String 01-JAN-1970 00:00:00
attribute time units String seconds since 1970-01-01T00:00:00Z
variable Sample_ID   int  
attribute Sample_ID actual_range int 10301, 380215
attribute Sample_ID long_name String Sample_id
attribute Sample_ID units String unitless
variable Station   float  
attribute Station actual_range float 1.0, 38.0
attribute Station long_name String Station
attribute Station units String unitless
variable Cast   int  
attribute Cast actual_range int 1, 14
attribute Cast long_name String Cast
attribute Cast units String unitless
variable Niskin   int  
attribute Niskin actual_range int 1, 35
attribute Niskin long_name String Niskin
attribute Niskin units String unitless
variable latitude   float  
attribute latitude _CoordinateAxisType String Lat
attribute latitude actual_range float -67.00024, -19.99984
attribute latitude axis String Y
attribute latitude ioos_category String Location
attribute latitude long_name String Latitude
attribute latitude standard_name String latitude
attribute latitude units String degrees_north
variable longitude   float  
attribute longitude _CoordinateAxisType String Lon
attribute longitude actual_range float -152.0003, -75.09732
attribute longitude axis String X
attribute longitude ioos_category String Location
attribute longitude long_name String Long
attribute longitude standard_name String longitude
attribute longitude units String degrees_east
variable Pressure   float  
attribute Pressure actual_range float 2.0, 5737.2
attribute Pressure long_name String Pressure
attribute Pressure units String decibars (db)
variable Practical_Salinity   float  
attribute Practical_Salinity actual_range float 33.4223, 36.2073
attribute Practical_Salinity long_name String Practical_salinity
attribute Practical_Salinity units String PSU
variable Total_Alkalinity_glass_bottle   float  
attribute Total_Alkalinity_glass_bottle actual_range float 2234.85, 2450.15
attribute Total_Alkalinity_glass_bottle long_name String Total_alkalinity_glass_bottle
attribute Total_Alkalinity_glass_bottle units String micromoles per kilogram seawater (umol/kg_sw)
variable Total_Alkalinity_Flag_glass_bottle   int  
attribute Total_Alkalinity_Flag_glass_bottle actual_range int 2, 6
attribute Total_Alkalinity_Flag_glass_bottle long_name String Total_alkalinity_flag_glass_bottle
attribute Total_Alkalinity_Flag_glass_bottle units String unitless
variable Total_Alkalinity_HDPE_bottle   float  
attribute Total_Alkalinity_HDPE_bottle actual_range float 2097.87, 2414.91
attribute Total_Alkalinity_HDPE_bottle long_name String Total_alkalinity_hdpe_bottle
attribute Total_Alkalinity_HDPE_bottle units String micromoles per kilogram seawater (umol/kg_sw)
variable Total_Alkalinity_Flag_HDPE_bottle   int  
attribute Total_Alkalinity_Flag_HDPE_bottle actual_range int 2, 6
attribute Total_Alkalinity_Flag_HDPE_bottle long_name String Total_alkalinity_flag_hdpe_bottle
attribute Total_Alkalinity_Flag_HDPE_bottle units String unitless

The information in the table above is also available in other file formats (.csv, .htmlTable, .itx, .json, .jsonlCSV1, .jsonlCSV, .jsonlKVP, .mat, .nc, .nccsv, .tsv, .xhtml) via a RESTful web service.


 
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