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     data   graph     files  public [Bivalve Boron Isotopes] - Boron isotope data from bivalves from 2022 tank experiment in the
Gulf of Maine, USA (Collaborative Research: Using multi-proxy paleo data to constrain natural
and anthropogenic hydrographic variability in the Gulf of Maine System over the last 250 years)
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The Dataset's Variables and Attributes

Row Type Variable Name Attribute Name Data Type Value
attribute NC_GLOBAL cdm_data_type String Other
attribute NC_GLOBAL Conventions String COARDS, CF-1.6, ACDD-1.3
attribute NC_GLOBAL creator_email String info at bco-dmo.org
attribute NC_GLOBAL creator_name String BCO-DMO
attribute NC_GLOBAL creator_url String https://www.bco-dmo.org/ (external link)
attribute NC_GLOBAL doi String 10.26008/1912/bco-dmo.995690.1
attribute NC_GLOBAL infoUrl String https://osprey.bco-dmo.org/dataset/995690 (external link)
attribute NC_GLOBAL institution String BCO-DMO
attribute NC_GLOBAL license String The data may be used and redistributed for free but is not intended
for legal use, since it may contain inaccuracies. Neither the data
Contributor, ERD, NOAA, nor the United States Government, nor any
of their employees or contractors, makes any warranty, express or
implied, including warranties of merchantability and fitness for a
particular purpose, or assumes any legal liability for the accuracy,
completeness, or usefulness, of this information.
attribute NC_GLOBAL sourceUrl String (local files)
attribute NC_GLOBAL summary String The boron isotopic composition (δ11Bc) of many marine carbonates provides insight into the pH at the site of calcification within biocalcifiers and, by extension, the pH of ambient seawater when the carbonate formed.

A 20.5-week flowthrough tank experiment was conducted in which four species of commercially important bivalves from the northwest Atlantic Ocean were grown in tanks with controlled pHT (pH 7.4 to 8.0) and temperature conditions (6 to 12 °C). A total of 106 shell samples from 99 individuals of adult and juvenile Arctica islandica (ocean quahog), juvenile Mercenaria mercenaria (northern quahog or hard clam), juvenile Mya arenaria (soft-shell clam), and juvenile Placopecten magellanicus (Atlantic sea scallop) were analyzed from this controlled experiment to assess the seawater pH, temperature, and growth rate controls on shell δ11Bc. Juvenile P. magellanicus and juvenile M. mercenaria demonstrated significant relationships (R≥0.60; p-value <0.006) between tank pHT and δ11Bc, suggesting potential utility as proxies for past ambient seawater pH. Conversely, the δ11Bc of juvenile A. islandica and juvenile M. arenaria did not yield a strong relationship with seawater pHT but instead yielded significant relationships with shell growth rate (linear extension), with a positive relationship for M. arenaria and a negative relationship for juvenile A. islandica. The δ11B results from the few (n=9) adult A. islandica shells measured show the most variability across the range of pH and temperatures (range of 16‰), and no significant relationship was found with seawater pH or growth rate. Despite rigorous oxidative cleaning of samples, the data suggest that adult A. islandica shells contain boron-rich organic phases resistant to traditional cleaning techniques.

The data on this site (summary file) include the average temperature, pH, and salinity used for the boron isotope analysis, in addition to the δ11B of the borate in water calculations, δ11B measured in the shells, the B/Ca ratio measured in the shells, and the delta pH values calculated using the above values.

Additional data include (temperature file) all temperature measurements from the tank experiment (every minute measurements) and daily averages. pH (pH file) and salinity (salinity file) data from weekly measurements are included. Data needed to perform the delta pH calculations are included (delta pH file).

The specimens grown in each tank that were used for boron isotope measurements are also included (boron specimens by tank file). This file specifies the number and species that were grown under the various tank conditions.
attribute NC_GLOBAL title String [Bivalve Boron Isotopes] - Boron isotope data from bivalves from 2022 tank experiment in the Gulf of Maine, USA (Collaborative Research: Using multi-proxy paleo data to constrain natural and anthropogenic hydrographic variability in the Gulf of Maine System over the last 250 years)
variable SampleID   String  
attribute SampleID long_name String Sampleid
attribute SampleID units String unitless
variable Sample_species   String  
attribute Sample_species long_name String Sample_species
attribute Sample_species units String unitless
variable Sample_description   String  
attribute Sample_description long_name String Sample_description
attribute Sample_description units String unitless
variable Average_temperature   float  
attribute Average_temperature actual_range float 6.0, 12.2
attribute Average_temperature long_name String Average_temperature
attribute Average_temperature units String degrees Celsius
variable Average_pHT   float  
attribute Average_pHT actual_range float 7.39, 8.05
attribute Average_pHT long_name String Average_pht
attribute Average_pHT units String pH units
variable Average_salinity   float  
attribute Average_salinity actual_range float 31.96, 32.146
attribute Average_salinity long_name String Average_salinity
attribute Average_salinity units String psu
variable boron_isotope_value_borate_ion   float  
attribute boron_isotope_value_borate_ion actual_range float 12.99, 15.83
attribute boron_isotope_value_borate_ion long_name String Boron_isotope_value_borate_ion
attribute boron_isotope_value_borate_ion units String per mil (‰, water)
variable boron_isotope_value_shell   float  
attribute boron_isotope_value_shell actual_range float 2.5, 19.25
attribute boron_isotope_value_shell long_name String Boron_isotope_value_shell
attribute boron_isotope_value_shell units String per mil (‰)
variable boron_calcium_ratio   int  
attribute boron_calcium_ratio actual_range int 16, 105
attribute boron_calcium_ratio long_name String Boron_calcium_ratio
attribute boron_calcium_ratio units String (umol/mol)
variable delta_pH   float  
attribute delta_pH actual_range float -2.279, 0.524
attribute delta_pH long_name String Delta_ph
attribute delta_pH units String pH units

The information in the table above is also available in other file formats (.csv, .htmlTable, .itx, .json, .jsonlCSV1, .jsonlCSV, .jsonlKVP, .mat, .nc, .nccsv, .tsv, .xhtml) via a RESTful web service.


 
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