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Dataset Title: | [Organic Phosphorus NEXFS Standards] - Near Edge X-ray Fluorescence Spectroscopy Data for standard organic phosphorus compounds (P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea) |
Institution: | BCO-DMO (Dataset ID: bcodmo_dataset_762119) |
Information: | Summary | License | ISO 19115 | Metadata | Background | Files | Make a graph |
Attributes { s { Energy { Float32 _FillValue NaN; Float32 actual_range 2110.0, 2190.0; String bcodmo_name "unknown"; String description "X-ray energy"; String long_name "Energy"; String units "nd"; } Two_aminoethylphosphonic_acid { Float32 _FillValue NaN; Float32 actual_range -0.0282, 2.8283; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 2041-14-7"; String long_name "Two Aminoethylphosphonic Acid"; String units "x-ray fluorescence counts"; } Ammonium_OO_diethyldithiophosphate { Float32 _FillValue NaN; Float32 actual_range -0.0209, 1.8239; String bcodmo_name "unknown"; Float64 colorBarMaximum 5.0; Float64 colorBarMinimum 0.0; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 1068-22-0"; String long_name "Mole Concentration Of Ammonium In Sea Water"; String units "x-ray fluorescence counts"; } Ammonium_Polyphosphate { Float32 _FillValue NaN; Float32 actual_range -0.0259, 2.5793; String bcodmo_name "unknown"; Float64 colorBarMaximum 5.0; Float64 colorBarMinimum 0.0; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 68333-79-9"; String long_name "Mole Concentration Of Ammonium In Sea Water"; String units "x-ray fluorescence counts"; } Adenosine_5prime_triphosphate { Float32 _FillValue NaN; Float32 actual_range -0.0102, 2.7108; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 51963-61-2"; String long_name "Mass Concentration Of Phosphate In Sea Water"; String units "x-ray fluorescence counts"; } Glycerol_Phosphate { Float32 _FillValue NaN; Float32 actual_range -0.0099, 1.7837; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 55073-41-1"; String long_name "Mass Concentration Of Phosphate In Sea Water"; String units "x-ray fluorescence counts"; } Hexametaphosphate { Float32 _FillValue NaN; Float32 actual_range -0.21, 2.127; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 68915-31-1"; String long_name "Mass Concentration Of Phosphate In Sea Water"; String units "x-ray fluorescence counts"; } Polyphosphate_CL15 { Float32 _FillValue NaN; Float32 actual_range -0.0104, 1.4542; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. Chain Length 15"; String long_name "Mass Concentration Of Phosphate In Sea Water"; String units "x-ray fluorescence counts"; } Sodium_tripolyphosphate { Float32 _FillValue NaN; Float32 actual_range -0.0055, 1.7077; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 7758-29-4"; String long_name "Mass Concentration Of Phosphate In Sea Water"; String units "x-ray fluorescence counts"; } O_Phospho_L_Serine { Float32 _FillValue NaN; Float32 actual_range -0.2451, 2.2487; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 407-41-0"; String long_name "O Phospho L Serine"; String units "x-ray fluorescence counts"; } O_Phosphorylethanolamine { Float32 _FillValue NaN; Float32 actual_range -0.4279, 1.9036; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 1071-23-4"; String long_name "O Phosphorylethanolamine"; String units "x-ray fluorescence counts"; } Propylenediphosphonic_Acid { Float32 _FillValue NaN; Float32 actual_range -0.0058, 2.0283; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 4671-82-3"; String long_name "Propylenediphosphonic Acid"; String units "x-ray fluorescence counts"; } Phosphotidylcholine { Float32 _FillValue NaN; Float32 actual_range -0.0073, 1.8211; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 97281-47-5"; String long_name "Phosphotidylcholine"; String units "x-ray fluorescence counts"; } Phytic_Acid { Float32 _FillValue NaN; Float32 actual_range -0.0051, 1.3673; String bcodmo_name "unknown"; String description "Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 83-86-3"; String long_name "Phytic Acid"; String units "x-ray fluorescence counts"; } } NC_GLOBAL { String access_formats ".htmlTable,.csv,.json,.mat,.nc,.tsv"; String acquisition_description "Methodology: X-ray spectromicroscopy data were collected using an energy dispersive silicon drift detector (Ketek with a 5mm2 sensitive area). A flow of helium was introduced between the X-ray optical hardware and the sample to reduce X-ray backscatter. An in-line monitor stick composed of hydroxyapatite was measured with each sample in order to identify and correct for any potential drift in monochrometer energy calibration that occurred during analyses (de Jonge et al., 2010). Clean areas of Teflon and cellulose acetate filters were examined as blanks and showed negligible background signal. The data for an individual P-NEXFS spectrum were normalized to create a relative intensity value ofapproximately 1 for post-edge area of the spectra (>2160 eV). Sampling and analytical procedures: Phosphorus compounds were obtained from chemical supply houses. See papers cited below for details. Instruments: X-ray fluorescence microscope located at beamline 2-ID-B at the Advanced Photon Source, Argonne National Laboratory. The beamline is optimized to examine samples over a 1\\u20134 keV energy range using a focused X-ray beam with a spot size of approximately 60 nanometers squared . The energy was calibrated using a NIST standard reference material SRM2910 calcium hydroxyapatite. The whiteline energy of the standard was set to 2153 eV. Data processing: P-NEXFS data were normalized to create a relative intensity value of approximately 1 for post-edge area of the spectra."; String awards_0_award_nid "753301"; String awards_0_award_number "OCE-1357375"; String awards_0_data_url "http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1357375"; String awards_0_funder_name "NSF Division of Ocean Sciences"; String awards_0_funding_acronym "NSF OCE"; String awards_0_funding_source_nid "355"; String awards_0_program_manager "Henrietta N Edmonds"; String awards_0_program_manager_nid "51517"; String cdm_data_type "Other"; String comment "Phosphorus NEXFS Standards PI: Ellery Ingall (GA Tech) Version date: 13-March-2019"; String Conventions "COARDS, CF-1.6, ACDD-1.3"; String creator_email "info@bco-dmo.org"; String creator_name "BCO-DMO"; String creator_type "institution"; String creator_url "https://www.bco-dmo.org/"; String data_source "extract_data_as_tsv version 2.3 19 Dec 2019"; String date_created "2019-03-13T16:31:41Z"; String date_modified "2019-03-29T19:27:05Z"; String defaultDataQuery "&time<now"; String doi "10.1575/1912/bco-dmo.762119.1"; String history "2024-12-21T15:43:07Z (local files) 2024-12-21T15:43:07Z https://erddap.bco-dmo.org/erddap/tabledap/bcodmo_dataset_762119.html"; String infoUrl "https://www.bco-dmo.org/dataset/762119"; String institution "BCO-DMO"; String instruments_0_dataset_instrument_description "X-ray fluorescence microscope located at beamline 2-ID-B at the Advanced Photon Source, Argonne National Laboratory. The beamline is optimized to examine samples over a 1–4 keV energy range using a focused X-ray beam with a spot size of approximately 60 nanometers squared . The energy was calibrated using a NIST standard reference material SRM2910 calcium hydroxyapatite. The whiteline energy of the standard was set to 2153 eV."; String instruments_0_dataset_instrument_nid "762133"; String instruments_0_description "Instruments that generate enlarged images of samples using the phenomena of fluorescence and phosphorescence instead of, or in addition to, reflection and absorption of visible light. Includes conventional and inverted instruments."; String instruments_0_instrument_external_identifier "https://vocab.nerc.ac.uk/collection/L05/current/LAB06/"; String instruments_0_instrument_name "Microscope-Fluorescence"; String instruments_0_instrument_nid "695"; String instruments_0_supplied_name "X-ray fluorescence microscope"; String keywords "acid, Adenosine_5prime_triphosphate, aminoethylphosphonic, ammonia, ammonium, Ammonium_OO_diethyldithiophosphate, Ammonium_Polyphosphate, bco, bco-dmo, biological, chemical, chemistry, concentration, data, dataset, dmo, earth, Earth Science > Oceans > Ocean Chemistry > Ammonia, Earth Science > Oceans > Ocean Chemistry > Phosphate, energy, erddap, Glycerol_Phosphate, Hexametaphosphate, management, mass, mass_concentration_of_phosphate_in_sea_water, mole, mole_concentration_of_ammonium_in_sea_water, nh4, O_Phospho_L_Serine, O_Phosphorylethanolamine, ocean, oceanography, oceans, office, phosphate, phospho, phosphorylethanolamine, phosphotidylcholine, phytic, Phytic_Acid, po4, Polyphosphate_CL15, preliminary, propylenediphosphonic, Propylenediphosphonic_Acid, science, sea, seawater, serine, Sodium_tripolyphosphate, two, Two_aminoethylphosphonic_acid, water"; String keywords_vocabulary "GCMD Science Keywords"; String license "https://www.bco-dmo.org/dataset/762119/license"; String metadata_source "https://www.bco-dmo.org/api/dataset/762119"; String param_mapping "{'762119': {}}"; String parameter_source "https://www.bco-dmo.org/mapserver/dataset/762119/parameters"; String people_0_affiliation "Georgia Institute of Technology"; String people_0_affiliation_acronym "Georgia Tech"; String people_0_person_name "Ellery Ingall"; String people_0_person_nid "645498"; String people_0_role "Principal Investigator"; String people_0_role_type "originator"; String people_1_affiliation "Woods Hole Oceanographic Institution"; String people_1_affiliation_acronym "WHOI BCO-DMO"; String people_1_person_name "Shannon Rauch"; String people_1_person_nid "51498"; String people_1_role "BCO-DMO Data Manager"; String people_1_role_type "related"; String project "Aerosol P"; String projects_0_acronym "Aerosol P"; String projects_0_description "NSF Award Abstract: Primary nutrients, such as nitrogen and phosphorus, are critical for all life on earth, and limited quantities in the marine environment can inhibit primary productivity. Atmospheric aerosols are a significant source of these nutrients to nutrient-poor ocean regions, such as the phosphorus-limited Mediterranean Sea. The availability of phosphorus in aerosols has traditionally been linked to the composition and abundance of different phosphorus phases present. Unfortunately, investigating phosphorus composition in aerosols has been challenging due to methodological limitations until recently. In this study, researchers from Georgia Tech will use a new technique known as synchrotron-based P Near Edge X-ray Fluorescence Spectroscopy, in conjunction with X-ray fluorescence microscopy, to examine the diversity of aerosol phosphorus phases delivered to the Mediterranean Sea. By defining the relationship between air mass source region, aerosol composition, and bioavailability, results from this work will improve current knowledge of the factors regulating productivity in the Mediterranean Sea and help to clarify the potential response of this region to different climate change scenarios. Broader Impacts: In addition to the valuable insights this project will provide on the controls on productivity and nutrient cycling in the Mediterranean Sea, this study will further education of young scientists, broaden participation of under-represented groups in ocean science, and enhance research infrastructure."; String projects_0_end_date "2018-07"; String projects_0_geolocation "Mediterranean"; String projects_0_name "P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea"; String projects_0_project_nid "753302"; String projects_0_start_date "2014-02"; String publisher_name "Biological and Chemical Oceanographic Data Management Office (BCO-DMO)"; String publisher_type "institution"; String sourceUrl "(local files)"; String standard_name_vocabulary "CF Standard Name Table v55"; String summary "Near Edge X-ray Fluorescence Spectroscopy Data for standard organic phosphorus compounds."; String title "[Organic Phosphorus NEXFS Standards] - Near Edge X-ray Fluorescence Spectroscopy Data for standard organic phosphorus compounds (P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea)"; String version "1"; String xml_source "osprey2erddap.update_xml() v1.3"; } }
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