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     data   graph     files  public [Organic Phosphorus NEXFS Standards] - Near Edge X-ray Fluorescence Spectroscopy Data for
standard organic phosphorus compounds (P-NEXFS investigation of the influence of aerosol
phosphorus on the Mediterranean Sea)
   ?        I   M   background (external link) RSS Subscribe BCO-DMO bcodmo_dataset_762119

The Dataset's Variables and Attributes

Row Type Variable Name Attribute Name Data Type Value
attribute NC_GLOBAL access_formats String .htmlTable,.csv,.json,.mat,.nc,.tsv
attribute NC_GLOBAL acquisition_description String Methodology: X-ray spectromicroscopy data were collected using an energy
dispersive silicon drift detector (Ketek with a 5mm2 sensitive area). A flow
of helium was introduced between the X-ray optical hardware and the sample to
reduce X-ray backscatter. An in-line monitor stick composed of hydroxyapatite
was measured with each sample in order to identify and correct for any
potential drift in monochrometer energy calibration that occurred during
analyses (de Jonge et al., 2010). Clean areas of Teflon and cellulose acetate
filters were examined as blanks and showed negligible background signal. The
data for an individual P-NEXFS spectrum were normalized to create a relative
intensity value ofapproximately 1 for post-edge area of the spectra (>2160
eV).

Sampling and analytical procedures: Phosphorus compounds were obtained from
chemical supply houses. See papers cited below for details.

Instruments: X-ray fluorescence microscope located at beamline 2-ID-B at the
Advanced Photon Source, Argonne National Laboratory. The beamline is optimized
to examine samples over a 1\u20134 keV energy range using a focused X-ray beam
with a spot size of approximately 60 nanometers squared . The energy was
calibrated using a NIST standard reference material SRM2910 calcium
hydroxyapatite. The whiteline energy of the standard was set to 2153 eV.

Data processing: P-NEXFS data were normalized to create a relative intensity
value of approximately 1 for post-edge area of the spectra.
attribute NC_GLOBAL awards_0_award_nid String 753301
attribute NC_GLOBAL awards_0_award_number String OCE-1357375
attribute NC_GLOBAL awards_0_data_url String http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1357375 (external link)
attribute NC_GLOBAL awards_0_funder_name String NSF Division of Ocean Sciences
attribute NC_GLOBAL awards_0_funding_acronym String NSF OCE
attribute NC_GLOBAL awards_0_funding_source_nid String 355
attribute NC_GLOBAL awards_0_program_manager String Henrietta N Edmonds
attribute NC_GLOBAL awards_0_program_manager_nid String 51517
attribute NC_GLOBAL cdm_data_type String Other
attribute NC_GLOBAL comment String Phosphorus NEXFS Standards
PI: Ellery Ingall (GA Tech)
Version date: 13-March-2019
attribute NC_GLOBAL Conventions String COARDS, CF-1.6, ACDD-1.3
attribute NC_GLOBAL creator_email String info at bco-dmo.org
attribute NC_GLOBAL creator_name String BCO-DMO
attribute NC_GLOBAL creator_type String institution
attribute NC_GLOBAL creator_url String https://www.bco-dmo.org/ (external link)
attribute NC_GLOBAL data_source String extract_data_as_tsv version 2.3 19 Dec 2019
attribute NC_GLOBAL date_created String 2019-03-13T16:31:41Z
attribute NC_GLOBAL date_modified String 2019-03-29T19:27:05Z
attribute NC_GLOBAL defaultDataQuery String &time<now
attribute NC_GLOBAL doi String 10.1575/1912/bco-dmo.762119.1
attribute NC_GLOBAL infoUrl String https://www.bco-dmo.org/dataset/762119 (external link)
attribute NC_GLOBAL institution String BCO-DMO
attribute NC_GLOBAL instruments_0_dataset_instrument_description String X-ray fluorescence microscope located at beamline 2-ID-B at the Advanced Photon Source, Argonne National Laboratory. The beamline is optimized to examine samples over a 1–4 keV energy range using a focused X-ray beam with a spot size of approximately 60 nanometers squared . The energy was calibrated using a NIST standard reference material SRM2910 calcium hydroxyapatite. The whiteline energy of the standard was set to 2153 eV.
attribute NC_GLOBAL instruments_0_dataset_instrument_nid String 762133
attribute NC_GLOBAL instruments_0_description String Instruments that generate enlarged images of samples using the phenomena of fluorescence and phosphorescence instead of, or in addition to, reflection and absorption of visible light. Includes conventional and inverted instruments.
attribute NC_GLOBAL instruments_0_instrument_external_identifier String https://vocab.nerc.ac.uk/collection/L05/current/LAB06/ (external link)
attribute NC_GLOBAL instruments_0_instrument_name String Microscope-Fluorescence
attribute NC_GLOBAL instruments_0_instrument_nid String 695
attribute NC_GLOBAL instruments_0_supplied_name String X-ray fluorescence microscope
attribute NC_GLOBAL keywords String acid, Adenosine_5prime_triphosphate, aminoethylphosphonic, ammonia, ammonium, Ammonium_OO_diethyldithiophosphate, Ammonium_Polyphosphate, bco, bco-dmo, biological, chemical, chemistry, concentration, data, dataset, dmo, earth, Earth Science > Oceans > Ocean Chemistry > Ammonia, Earth Science > Oceans > Ocean Chemistry > Phosphate, energy, erddap, Glycerol_Phosphate, Hexametaphosphate, management, mass, mass_concentration_of_phosphate_in_sea_water, mole, mole_concentration_of_ammonium_in_sea_water, nh4, O_Phospho_L_Serine, O_Phosphorylethanolamine, ocean, oceanography, oceans, office, phosphate, phospho, phosphorylethanolamine, phosphotidylcholine, phytic, Phytic_Acid, po4, Polyphosphate_CL15, preliminary, propylenediphosphonic, Propylenediphosphonic_Acid, science, sea, seawater, serine, Sodium_tripolyphosphate, two, Two_aminoethylphosphonic_acid, water
attribute NC_GLOBAL keywords_vocabulary String GCMD Science Keywords
attribute NC_GLOBAL license String https://www.bco-dmo.org/dataset/762119/license (external link)
attribute NC_GLOBAL metadata_source String https://www.bco-dmo.org/api/dataset/762119 (external link)
attribute NC_GLOBAL param_mapping String {'762119': {}}
attribute NC_GLOBAL parameter_source String https://www.bco-dmo.org/mapserver/dataset/762119/parameters (external link)
attribute NC_GLOBAL people_0_affiliation String Georgia Institute of Technology
attribute NC_GLOBAL people_0_affiliation_acronym String Georgia Tech
attribute NC_GLOBAL people_0_person_name String Ellery Ingall
attribute NC_GLOBAL people_0_person_nid String 645498
attribute NC_GLOBAL people_0_role String Principal Investigator
attribute NC_GLOBAL people_0_role_type String originator
attribute NC_GLOBAL people_1_affiliation String Woods Hole Oceanographic Institution
attribute NC_GLOBAL people_1_affiliation_acronym String WHOI BCO-DMO
attribute NC_GLOBAL people_1_person_name String Shannon Rauch
attribute NC_GLOBAL people_1_person_nid String 51498
attribute NC_GLOBAL people_1_role String BCO-DMO Data Manager
attribute NC_GLOBAL people_1_role_type String related
attribute NC_GLOBAL project String Aerosol P
attribute NC_GLOBAL projects_0_acronym String Aerosol P
attribute NC_GLOBAL projects_0_description String NSF Award Abstract:
Primary nutrients, such as nitrogen and phosphorus, are critical for all life on earth, and limited quantities in the marine environment can inhibit primary productivity. Atmospheric aerosols are a significant source of these nutrients to nutrient-poor ocean regions, such as the phosphorus-limited Mediterranean Sea. The availability of phosphorus in aerosols has traditionally been linked to the composition and abundance of different phosphorus phases present. Unfortunately, investigating phosphorus composition in aerosols has been challenging due to methodological limitations until recently. In this study, researchers from Georgia Tech will use a new technique known as synchrotron-based P Near Edge X-ray Fluorescence Spectroscopy, in conjunction with X-ray fluorescence microscopy, to examine the diversity of aerosol phosphorus phases delivered to the Mediterranean Sea. By defining the relationship between air mass source region, aerosol composition, and bioavailability, results from this work will improve current knowledge of the factors regulating productivity in the Mediterranean Sea and help to clarify the potential response of this region to different climate change scenarios.
Broader Impacts: In addition to the valuable insights this project will provide on the controls on productivity and nutrient cycling in the Mediterranean Sea, this study will further education of young scientists, broaden participation of under-represented groups in ocean science, and enhance research infrastructure.
attribute NC_GLOBAL projects_0_end_date String 2018-07
attribute NC_GLOBAL projects_0_geolocation String Mediterranean
attribute NC_GLOBAL projects_0_name String P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea
attribute NC_GLOBAL projects_0_project_nid String 753302
attribute NC_GLOBAL projects_0_start_date String 2014-02
attribute NC_GLOBAL publisher_name String Biological and Chemical Oceanographic Data Management Office (BCO-DMO)
attribute NC_GLOBAL publisher_type String institution
attribute NC_GLOBAL sourceUrl String (local files)
attribute NC_GLOBAL standard_name_vocabulary String CF Standard Name Table v55
attribute NC_GLOBAL summary String Near Edge X-ray Fluorescence Spectroscopy Data for standard organic phosphorus compounds.
attribute NC_GLOBAL title String [Organic Phosphorus NEXFS Standards] - Near Edge X-ray Fluorescence Spectroscopy Data for standard organic phosphorus compounds (P-NEXFS investigation of the influence of aerosol phosphorus on the Mediterranean Sea)
attribute NC_GLOBAL version String 1
attribute NC_GLOBAL xml_source String osprey2erddap.update_xml() v1.3
variable Energy   float  
attribute Energy _FillValue float NaN
attribute Energy actual_range float 2110.0, 2190.0
attribute Energy bcodmo_name String unknown
attribute Energy description String X-ray energy
attribute Energy long_name String Energy
attribute Energy units String nd
variable Two_aminoethylphosphonic_acid   float  
attribute Two_aminoethylphosphonic_acid _FillValue float NaN
attribute Two_aminoethylphosphonic_acid actual_range float -0.0282, 2.8283
attribute Two_aminoethylphosphonic_acid bcodmo_name String unknown
attribute Two_aminoethylphosphonic_acid description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 2041-14-7
attribute Two_aminoethylphosphonic_acid long_name String Two Aminoethylphosphonic Acid
attribute Two_aminoethylphosphonic_acid units String x-ray fluorescence counts
variable Ammonium_OO_diethyldithiophosphate   float  
attribute Ammonium_OO_diethyldithiophosphate _FillValue float NaN
attribute Ammonium_OO_diethyldithiophosphate actual_range float -0.0209, 1.8239
attribute Ammonium_OO_diethyldithiophosphate bcodmo_name String unknown
attribute Ammonium_OO_diethyldithiophosphate colorBarMaximum double 5.0
attribute Ammonium_OO_diethyldithiophosphate colorBarMinimum double 0.0
attribute Ammonium_OO_diethyldithiophosphate description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 1068-22-0
attribute Ammonium_OO_diethyldithiophosphate long_name String Mole Concentration Of Ammonium In Sea Water
attribute Ammonium_OO_diethyldithiophosphate units String x-ray fluorescence counts
variable Ammonium_Polyphosphate   float  
attribute Ammonium_Polyphosphate _FillValue float NaN
attribute Ammonium_Polyphosphate actual_range float -0.0259, 2.5793
attribute Ammonium_Polyphosphate bcodmo_name String unknown
attribute Ammonium_Polyphosphate colorBarMaximum double 5.0
attribute Ammonium_Polyphosphate colorBarMinimum double 0.0
attribute Ammonium_Polyphosphate description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 68333-79-9
attribute Ammonium_Polyphosphate long_name String Mole Concentration Of Ammonium In Sea Water
attribute Ammonium_Polyphosphate units String x-ray fluorescence counts
variable Adenosine_5prime_triphosphate   float  
attribute Adenosine_5prime_triphosphate _FillValue float NaN
attribute Adenosine_5prime_triphosphate actual_range float -0.0102, 2.7108
attribute Adenosine_5prime_triphosphate bcodmo_name String unknown
attribute Adenosine_5prime_triphosphate description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 51963-61-2
attribute Adenosine_5prime_triphosphate long_name String Mass Concentration Of Phosphate In Sea Water
attribute Adenosine_5prime_triphosphate units String x-ray fluorescence counts
variable Glycerol_Phosphate   float  
attribute Glycerol_Phosphate _FillValue float NaN
attribute Glycerol_Phosphate actual_range float -0.0099, 1.7837
attribute Glycerol_Phosphate bcodmo_name String unknown
attribute Glycerol_Phosphate description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 55073-41-1
attribute Glycerol_Phosphate long_name String Mass Concentration Of Phosphate In Sea Water
attribute Glycerol_Phosphate units String x-ray fluorescence counts
variable Hexametaphosphate   float  
attribute Hexametaphosphate _FillValue float NaN
attribute Hexametaphosphate actual_range float -0.21, 2.127
attribute Hexametaphosphate bcodmo_name String unknown
attribute Hexametaphosphate description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 68915-31-1
attribute Hexametaphosphate long_name String Mass Concentration Of Phosphate In Sea Water
attribute Hexametaphosphate units String x-ray fluorescence counts
variable Polyphosphate_CL15   float  
attribute Polyphosphate_CL15 _FillValue float NaN
attribute Polyphosphate_CL15 actual_range float -0.0104, 1.4542
attribute Polyphosphate_CL15 bcodmo_name String unknown
attribute Polyphosphate_CL15 description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. Chain Length 15
attribute Polyphosphate_CL15 long_name String Mass Concentration Of Phosphate In Sea Water
attribute Polyphosphate_CL15 units String x-ray fluorescence counts
variable Sodium_tripolyphosphate   float  
attribute Sodium_tripolyphosphate _FillValue float NaN
attribute Sodium_tripolyphosphate actual_range float -0.0055, 1.7077
attribute Sodium_tripolyphosphate bcodmo_name String unknown
attribute Sodium_tripolyphosphate description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 7758-29-4
attribute Sodium_tripolyphosphate long_name String Mass Concentration Of Phosphate In Sea Water
attribute Sodium_tripolyphosphate units String x-ray fluorescence counts
variable O_Phospho_L_Serine   float  
attribute O_Phospho_L_Serine _FillValue float NaN
attribute O_Phospho_L_Serine actual_range float -0.2451, 2.2487
attribute O_Phospho_L_Serine bcodmo_name String unknown
attribute O_Phospho_L_Serine description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 407-41-0
attribute O_Phospho_L_Serine long_name String O Phospho L Serine
attribute O_Phospho_L_Serine units String x-ray fluorescence counts
variable O_Phosphorylethanolamine   float  
attribute O_Phosphorylethanolamine _FillValue float NaN
attribute O_Phosphorylethanolamine actual_range float -0.4279, 1.9036
attribute O_Phosphorylethanolamine bcodmo_name String unknown
attribute O_Phosphorylethanolamine description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 1071-23-4
attribute O_Phosphorylethanolamine long_name String O Phosphorylethanolamine
attribute O_Phosphorylethanolamine units String x-ray fluorescence counts
variable Propylenediphosphonic_Acid   float  
attribute Propylenediphosphonic_Acid _FillValue float NaN
attribute Propylenediphosphonic_Acid actual_range float -0.0058, 2.0283
attribute Propylenediphosphonic_Acid bcodmo_name String unknown
attribute Propylenediphosphonic_Acid description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 4671-82-3
attribute Propylenediphosphonic_Acid long_name String Propylenediphosphonic Acid
attribute Propylenediphosphonic_Acid units String x-ray fluorescence counts
variable Phosphotidylcholine   float  
attribute Phosphotidylcholine _FillValue float NaN
attribute Phosphotidylcholine actual_range float -0.0073, 1.8211
attribute Phosphotidylcholine bcodmo_name String unknown
attribute Phosphotidylcholine description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 97281-47-5
attribute Phosphotidylcholine long_name String Phosphotidylcholine
attribute Phosphotidylcholine units String x-ray fluorescence counts
variable Phytic_Acid   float  
attribute Phytic_Acid _FillValue float NaN
attribute Phytic_Acid actual_range float -0.0051, 1.3673
attribute Phytic_Acid bcodmo_name String unknown
attribute Phytic_Acid description String Name of organic phosphorus compound. Units (x-ray fluorescence counts) are normalized to incoming radiation. CAS# 83-86-3
attribute Phytic_Acid long_name String Phytic Acid
attribute Phytic_Acid units String x-ray fluorescence counts

The information in the table above is also available in other file formats (.csv, .htmlTable, .itx, .json, .jsonlCSV1, .jsonlCSV, .jsonlKVP, .mat, .nc, .nccsv, .tsv, .xhtml) via a RESTful web service.


 
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